Skip to main content
SpringerLink
Log in

Synthesis of ZSM-5 type zeolites with and without template and evaluation of physicochemical properties and aniline alkylation activity

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

ZSM-5 zeolite containing SiO2/Al2O3 = 28 was synthesised by hydrothermal process with and without template. Characterisation of the zeolites was done using XRD, IR, NMR, SEM and BET surface area measurements. Acidity of the zeolites was measured by ammonia adsorption-desorption. Catalytic activity of HZSM-5 zeolites was evaluated by aniline alkylation, cumene dealkylation, alkylation of benzene with ethylene and propylene and isomerisation ofm-xylene. Catalytic activity is discussed from the point of view of zeolite acidity and morphology.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F.J. van der Gaag, J.C. Jamen and H. van Bekkum, Stud. Surf. Sci. Catal. 24 (1985) 81.

    Google Scholar 

  2. M. Schwarz, M. Kojima and C.T. O'Connor, Appl. Catal. 73 (1991) 313.

    Google Scholar 

  3. S. Mintova and V. Valtcher, Zeolites 13 (1993) 305.

    Google Scholar 

  4. S.I. Zones, Zeolites 9 (1989) 458.

    Google Scholar 

  5. E. Narita, K. Sato, N. Yatabe and T. Okabe, Ind. Eng. Chem. Prod. Res. Dev. 24 (1985) 507.

    Google Scholar 

  6. F.J. Dai, M. Suzuki, H. Takahashi and Y. Saito,New Developments in Zeolite Science and Technology, Proc. 7th Int. Zeol. Conf., eds. Y. Murakami, A. Lizima and J.W. Ward (Elsevier, Amsterdam, 1986).

    Google Scholar 

  7. V.P. Shiralkar and A. Clearfield, Zeolites 9 (1989) 363.

    Google Scholar 

  8. P.N. Joshi, A.A. Shaikh, V.R. Chumbhale, B.S. Rao and V.P. Shiralkar, J. Incl. Phen. Mol. Recog. Chem. 13 (1992) 171.

    Google Scholar 

  9. GB Patent 1,567,948 (1980).

  10. US Patent 4,257,885 (1981).

  11. T. Inui, N. Morinaga, T. Ishihara, T. Kanie and Y. Takegami, J. Catal. 79 (1983) 176.

    Google Scholar 

  12. E. Narita, K. Sato and T. Okabe, Chem. Lett. (1984) 1055.

  13. J.M. Berak and R. Mostowicz, Stud. Surf. Sci. Catal. 24 (1985) 47.

    Google Scholar 

  14. A. Tissler, P. Polanek, V. Girrbach, V. Muller and K.K. Unger, Stud. Surf. Sci. Catal. 46 (1989) 399.

    Google Scholar 

  15. P.A. Jacobs and J.A. Matens, Stud. Surf. Sci. Catal. 33 (1987) 134.

    Google Scholar 

  16. G. Coudurier, C. Naccache and J.C. Vedrine, J. Chem. Soc. Chem. Comm. (1982) 1413.

  17. J.C. Jansen, F.J. van der Gaag and H. van Bekkum, Zeolites 4 (1984) 369.

    Google Scholar 

  18. P.A. Jacobs, H.K. Beyer and J. Valyon, Zeolites 1 (1981) 161.

    Google Scholar 

  19. V.P. Shiralkar, P.N. Joshi, M.J. Eapen and B.S. Rao, Zeolites 11 (1991) 511.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Catalysis Section, Indian Institute of Chemical Technology, 500 007, Hyderabad, India

    S. Narayanan, Asima Sultana & K. Krishna

  2. Institut de Recherches sur la Catalyse (CNRS), 69626, Villeurbanne, Cedex, France

    Paul Mériaudeau & Claude Naccache

Authors
  1. S. Narayanan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Asima Sultana
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. Krishna
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Paul Mériaudeau
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Claude Naccache
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Narayanan, S., Sultana, A., Krishna, K. et al. Synthesis of ZSM-5 type zeolites with and without template and evaluation of physicochemical properties and aniline alkylation activity. Catal Lett 34, 129–138 (1995). https://doi.org/10.1007/BF00808329

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00808329

Keywords

Search

Navigation