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Methylbis(thiomethanolato)bismut(III) — Synthese, Charakterisierung und mikrobiologische Aktivität

Methylbis(thiomethanolato)bismuth(III)—Synthesis, characterization and bactericidal activity

  • Organische Chemie Und Biochemie
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Abstract

The reaction of methyldibromobismuth(III),MeBiBr2, with two equivalents of lithium thiomethanolate affords the new dithiolate complexMeBi(SMe)2 (1). This compound is interesting in terms of its strong biological activity.1H NMR and mass spectra of1 are discussed. As1 did not show characteristic metastable transitions in the MS under test conditions, ion genesis could partially be proved by using the isotopic labelled derivativeMe*Bi(SMe)2 (1*) (Me*=13CH3).

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Author notes

  1. Thomas Klapötke

    Present address: Department of Chemistry, University of New Brunswick, E3B 6E2, Fredericton, N.B., Canada

Authors and Affiliations

  1. Institut für Anorganische und Analytische Chemie, Technische Universität Berlin, D-1000, Berlin 12

    Thomas Klapötke

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  1. Thomas Klapötke
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Klapötke, T. Methylbis(thiomethanolato)bismut(III) — Synthese, Charakterisierung und mikrobiologische Aktivität. Monatsh Chem 119, 1317–1321 (1988). https://doi.org/10.1007/BF00808312

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  • DOI: https://doi.org/10.1007/BF00808312

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