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A new synthesis procedure for titanium-containing zeolites under strong alkaline conditions and the catalytic activity for partial oxidation and photocatalytic decomposition

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Abstract

A new synthesis procedure for titanium-containing aluminosilicate zeolites has been obtained using a clear colloidal dispersion (sol) which was prepared with titanium isopropoxide, water, hydrochloric acid and colloidal silica, Ludox. When NaY, KL, offretite, mordenite and ZSM-5 zeolites were crystallized from the sol following conventional hydrothermal crystallization procedures, all the aluminosilicate zeolites showed the same X-ray absorption fine structure at the Ti K edge indicating framework Ti. The zeolites showed remarkable catalytic activity for the partial oxidation of cyclohexene using H2O2 as an oxidant and the photocatalytic decomposition of trichloroethene using water.

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References

  1. M. Taramasso, G. Perego and B. Notari, US Patent 4,410,501.

  2. B. Notari, Catal. Today 18 (1993) 163.

    Google Scholar 

  3. J.S. Reddy and R. Kumar, Zeolites 12 (1992) 95.

    Google Scholar 

  4. T. Blasco, M.A. Camblor, A. Corma and J. Pérez-Pariente, J. Am. Chem. Soc. 115 (1993) 11806.

    Google Scholar 

  5. A. Corma, M.T. Navarro and J. Pérez-Pariente, J. Chem. Soc. Chem. Commun. (1994) 147.

  6. A. Tuel, Zeolites 15 (1995) 236.

    Google Scholar 

  7. D. Trong On, L. Bonneviot, A. Bittar, A. Sayari and S.J. Kaliaguine, J. Mol. Catal. 74 (1992) 233.

    Google Scholar 

  8. S. Bordiga, F. Boscherini, S. Coluccia, F. Genoni, C. Lamberti, G. Leofanti, L. Marchese, G. Petrini, G. Vlaic and A. Zecchina, Catal. Lett. 26 (1994) 195.

    Google Scholar 

  9. C.B. Khouw and M.E. Davis, J. Catal. 151 (1995) 77.

    Google Scholar 

  10. L.D. Rollmann and E.W. Valyocsik, in:Inorganic Synthesis, Vol. 22, ed. S.L. Holt Jr. (Wiley, New York, 1983) p. 61.

    Google Scholar 

  11. P.N. Joshi, A.N. Kotasthane and V.P. Shiralkair, Zeolites 10 (1990) 598.

    Google Scholar 

  12. D.W. Breck,Zeolite Molecular Sieves (Wiley, New York, 1974).

    Google Scholar 

  13. M.A. Fox and M.T. Dulay, Chem. Rev. 93 (1993) 341.

    Google Scholar 

  14. C. Pak, S.J. Cho, J.Y. Lee and R. Ryoo, J. Catal. 149 (1994) 61.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry and Center for Molecular Science, Korea Advanced Institute of Science and Technology, Taeduk Science Town, 305-701, Taejon, Korea

    Ja Hun Kwak, Sung June Cho & Ryong Ryoo

Authors
  1. Ja Hun Kwak
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  2. Sung June Cho
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  3. Ryong Ryoo
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Kwak, J.H., Cho, S.J. & Ryoo, R. A new synthesis procedure for titanium-containing zeolites under strong alkaline conditions and the catalytic activity for partial oxidation and photocatalytic decomposition. Catal Lett 37, 217–221 (1996). https://doi.org/10.1007/BF00807757

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  • DOI: https://doi.org/10.1007/BF00807757

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