Skip to main content
SpringerLink
Log in

On the chemistry of pyrrole pigments, XCVI: An efficient synthesis of corrphycenes

Zur Chemie von Pyrrolpigmenten, 96. Mitt.: Eine effiziente Synthese von Corrphycenen

  • Organische Chemie Und Biochemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

By means of copper catalyzed intramolecular coupling of the easily accessible 1,2-bis-(1-iodo-dipyrrin-9-yl)-ethanes and subsequent demetallation of the intermediate copper complexes corrphycenes could be prepared in nearly 40% overall yields.

Zusammenfassung

Durch Kupfer katalysierte intramolekulare Kupplung der leicht zugänglichen 1,2-bis-(1-Iod-dipyrrin-9-yl)-ethane und anschließende Demetallierung der gebildeten Kupferkomplexe ergibt Corrphycene in Gesamtausbeuten von fast 40%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Part XV: Chen Q-Q, Falk H (1995) Monatsh Chem126: 1323

    Google Scholar 

  2. Dolphin D (1979) The porphyrins. Academic Press, New York

    Google Scholar 

  3. Vogel E (1993) Pure Appl Chem65: 143

    Google Scholar 

  4. Sessler JL, Hemmi G, Mody Mit, 10. Mai 1995, Murai T, Burrell A, Young SW (1994) Acc Chem Res27: 43

    Google Scholar 

  5. Sessler JL, Brucker EA, Weghorn SJ, Kisters M, Schäfer M, Lex J, Vogel E (1994) Angew Chem106: 2402

    Google Scholar 

  6. McMurry JE (1989) Chem Rev89: 1513; Lenoir D (1989) Synthesis1989: 883 and references therein

    Google Scholar 

  7. For leading references see Falk H (1989) The chemistry of linear oligopyrroles and bile pigments. Springer, Wien New York

    Google Scholar 

  8. Chen Q-Q, Falk H (1995) Monatsh Chem126: 1233

    Google Scholar 

  9. Chen Q-Q, Falk H, Micura R (1995) Monatsh Chem126: 473

    Google Scholar 

  10. Paine III JB, Woodward RB, Dolphin D (1976) J Org Chem41, 2826

    Google Scholar 

  11. Fanta PE (1964) Chem Rev64: 613

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Chemie, Johannes Kepler Universität Linz, A-4040, Linz, Austria

    H. Falk & Q. -Q. Chen

Authors
  1. H. Falk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Q. -Q. Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Falk, H., Chen, Q.Q. On the chemistry of pyrrole pigments, XCVI: An efficient synthesis of corrphycenes. Monatsh Chem 127, 69–75 (1996). https://doi.org/10.1007/BF00807410

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00807410

Keywords

Search

Navigation