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The crystal structure of PbFe[AsO4][AsO3(OH)]

Die Kristallstruktur von PbFe[AsO4][AsO3(OH)]

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

Light green to nearly colourless crystals of PbFe[AsO4][AsO3(OH)] were synthesized under moderate hydrothermal conditions (a=4.846(2),b=8.482(4),c=15.560(6) Å, β=92.82(3)°, space group P21/n, Z=4). For a single-crystal structure determination, 110 variable parameters were refined toR=0.042,R w=0.031 (1545 X-ray reflections withF 0 >3σ(F 0) and sinϑ/λ⩽70°). The crystal structure is characterized by a three-dimensional corner-connection of the FeO6 octahedra with the arsenate tetrahedra and the protonated arsenate groups. Each two PbO7 polyhedra are edge-connected to Pb2O12 dimers which are located within interstitial holes.

Zusammenfassung

Hellgrüne bis nahezu farblose Kristalle von PbFe[AsO4][AsO3(OH)] wurden unter niedrig-hydrothermalen Bedingungen synthetisiert (a=4.846(2),b=8.482(4),c=15.560(6) Å, β=92.82(3)°, Raumgruppe P21/n, Z=4). Für die Einkristall-Strukturbestimmung wurden 110 freie Parameter aufR=0.042,R w=0.031 verfeinert (1545 Röntgenbeugungsreflexe mitF 0 >3σ(F 0) und sinϑ/λ⩽70°). Die Kristallstruktur wird durch eine dreidimensionale Ecken-Verknüpfung der FeO6-Oktaeder mit den Arsenattetraedern und den protonierten Arsenatgruppen charakterisiert. Jeweils zwei PbO7-Polyeder sind über eine Kante zu Pb2O12-Dimeren verknüpft, die in Zwischenräumen angeordnet sind.

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References

  1. Viswanathan K, Miehe G (1978) Z Krist148: 275

    Google Scholar 

  2. Wilson CC (1994) Mineral Mag58: 629

    Google Scholar 

  3. Worzala H, Howie RA, Jost KH (1991) Z Anorg Allgem Chem606: 213

    Google Scholar 

  4. Finney JJ (1963) Am Mineral48: 1

    Google Scholar 

  5. Hofmeister W, Tillmanns E (1978) Tschermaks Mineral Petrogr Mitt25: 153

    Google Scholar 

  6. Pring A, McBriar EM, Birch WD (1989) Am Mineral74: 1377

    Google Scholar 

  7. Tillmanns E, Gebert W (1973) Acta CrystB29: 2789

    Google Scholar 

  8. Pertlik F (1986) Acta CrystC42: 774

    Google Scholar 

  9. Effenberger H (1995) J Solid State Chem114: 413

    Google Scholar 

  10. Pertlik F (1986) Monatsh Chem117: 1343

    Google Scholar 

  11. Ghose G, Che'ng Wan (1979) Acta CrystB35: 819

    Google Scholar 

  12. Szymański JT (1988) Can Mineral26: 923

    Google Scholar 

  13. Basso R, Palenzona A, Zefiro L (1989) N Jahrb Mineral Monatsh1989: 300

    Google Scholar 

  14. Cocco G, Fanfani L, Zanazzi PF (1967) Z Krist124: 385

    Google Scholar 

  15. Medenbach O, Abraham K, Gebert W (1983) N Jahrb Mineral Mh1983: 289

    Google Scholar 

  16. Calos NJ, Kennard CHL, Davis RL (1990) Z Krist191: 125

    Google Scholar 

  17. Dai Y, Hughes JM, Moore PB (1991) Can Mineral29: 369

    Google Scholar 

  18. Rouse RC, Dunn PJ, Peacor DR (1984) Am Mineral69: 920

    Google Scholar 

  19. Fischer RX, Tillmanns E (1988) Acta CrystC44: 775

    Google Scholar 

  20. Brese NE, O'Keeffe M (1991) Acta CrystB47: 192

    Google Scholar 

  21. Dowty E (1991) Atoms, a computer program for displaying atomic structures, Version 2.0. Kingsport, TN

  22. Brunel-Laügt M, Guitel J-C (1977) Acta CrystB33: 937

    Google Scholar 

  23. Brunel-Laügt M, Tordjman I, Durif A (1976) Acta CrystB32: 3246

    Google Scholar 

  24. Fujita T, Kawada I, Kato K (1977) Acta CrystB33: 162

    Google Scholar 

  25. Otto HH (1979) Z Krist149: 197

    Google Scholar 

  26. Brandstätter F (1981) Z Krist155: 193

    Google Scholar 

  27. Averbuch-Pouchot MT, Durif A (1987) Acta CrystC43: 631

    Google Scholar 

  28. Gatehouse BM, Guddat LW (1987) Acta CrystC43: 1659

    Google Scholar 

  29. El-Horr N, Bagieu-Beucher M (1986) Acta CrystC42: 647

    Google Scholar 

  30. Ferraris G, Ivaldi G (1984) Acta CrystB40: 1

    Google Scholar 

  31. Brown ID, Altermatt D (1985) Acta CrystB41: 244

    Google Scholar 

  32. Wilson AJC (1992) International tables for crystallography, vol C. Kluwer Academic, Dordrecht Boston London

    Google Scholar 

  33. Sheldrick GM (1976) SHELX-76, programs for crystal structure determination. University of Cambridge

  34. Frenz BA, and Associates (1992) Inc., Personal SDP, College Station, TX

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Authors and Affiliations

  1. Institut für Mineralogie und Kristallographie, Universität Wien, A-1090, Wien, Austria

    H. Effenberger, C. Hejny & F. Pertlik

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  1. H. Effenberger
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  2. C. Hejny
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  3. F. Pertlik
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Effenberger, H., Hejny, C. & Pertlik, F. The crystal structure of PbFe[AsO4][AsO3(OH)]. Monatsh Chem 127, 127–133 (1996). https://doi.org/10.1007/BF00807393

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  • DOI: https://doi.org/10.1007/BF00807393

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