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Autocatalytic waves in the nitric acid-hydroxylamine system: analytical description of the wave velocity

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Abstract

It is shown that the velocity (c) of the autocatalytic travelling waves in the nitric acid-hydroxylamine system can be described by the formulac 2=4D{(3k 1/2)−k 2[NH3OH+]0} deduced from a previously proposed mechanism. Comparisons with other systems are included.

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References

  1. R. Gowland and G. Stedman, J. Chem. Soc. Chem. Commun. (1983) 1038.

  2. G. Stedman, E. Jones and M.S. Garley, React. Kinet. Catal. Lett. 42 (1990) 395.

    Google Scholar 

  3. M.S. Garley, E. Jones and G. Stedman, Phil. Trans. Roy. Soc. A 337 (1991) 237.

    Google Scholar 

  4. J.R. Pembridge and G. Stedman, J. Chem. Soc. Dalton (1979) 1657.

  5. R.J. Gowland and G. Stedman, J. Inorg. Nucl. Chem. 43 (1981) 2859.

    Google Scholar 

  6. G.C.M. Bourke and G. Stedman, J. Chem. Soc. Perkin Trans. 2 (1992) 161.

    Google Scholar 

  7. K. Showalter and J.J. Tyson, J. Chem. Educ. 64 (1987) 742.

    Google Scholar 

  8. J.H. Merkin, D.J. Needham and S.K. Scott, Proc. Roy. Soc. Lond. A 424 (1989) 187.

    Google Scholar 

  9. D.J. Needham and Q. Ji, Mech. Appl. Math. 45 (1992) 469.

    Google Scholar 

  10. G. Bazsa and I.R. Epstein, J. Phys. Chem. 89 (1985) 3050.

    Google Scholar 

  11. I. Nagypál, G. Bazsa and I.R. Epstein, J. Am. Chem. Soc. 108 (1986) 363.

    Google Scholar 

  12. G. Póta, I. Lengyel and G. Bazsa, J. Chem. Soc. Faraday Trans. I 85 (1989) 3871.

    Google Scholar 

  13. I. Nagy, G. Póta and G. Bazsa, J. Chem. Soc. Faraday Trans. 87 (1991) 3613.

    Google Scholar 

  14. G. Póta, I. Lengyel and G. Bazsa, J. Phys. Chem. 95 (1991) 4379.

    Google Scholar 

  15. M.R. Bennett, G.M. Brown, L. Maya and F.A. Posey, Inorg. Chem. 21 (1982) 2461.

    Google Scholar 

  16. H.N. Heckner and G. Schmid, Electrochim. Acta 16 (1971) 131.

    Google Scholar 

  17. G. Schmid and F. Bähr, Z. Phys. Chem. (Frankfurt) 41 (1964) 8.

    Google Scholar 

  18. H.S. Dosanjh, M.Phil. Thesis, University of Wales, UK (1991).

    Google Scholar 

  19. S.K. Scott and K. Showalter, J. Phys. Chem. 96 (1992) 8702.

    Google Scholar 

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Jones, E., Póta, G. & Stedman, G. Autocatalytic waves in the nitric acid-hydroxylamine system: analytical description of the wave velocity. Catal Lett 24, 211–214 (1994). https://doi.org/10.1007/BF00807391

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  • DOI: https://doi.org/10.1007/BF00807391

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