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Catalysis Letters

, Volume 22, Issue 4, pp 327–331 | Cite as

Chlorine-free iron-ruthenium catalyst for the water-gas shift reaction

  • Anna Basińska
  • Florian Domka
Article

Abstract

We present results of studies on the activity of chlorine-free iron-ruthenium catalysts in the water-gas shift reaction. The catalysts were prepared by impregnation of calcination products of α-, β-, γ-, δ-iron oxide-hydroxides with Ru3(CO)12. For two iron oxides (from α- and δ-FeOOH) the reaction rate constants are considerably higher than those of reactions with other catalysts based on RuCl3. Among the catalysts used, those obtained by impregnation of δ-FeOOH calcination product with Ru3(CO)12 appeared to be the most active.

Keywords

Ruthenium catalysts alloy catalysts water-gas shift reactions 

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Copyright information

© J.C. Baltzer AG, Science Publishers 1993

Authors and Affiliations

  • Anna Basińska
    • 1
  • Florian Domka
    • 1
  1. 1.Department of Kinetics and Catalysis, Faculty of ChemistryAdam Mickiewicz UniversityPoznańPoland

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