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Reduction of supported cobalt catalysts by hydrogen

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Abstract

The reduction of cobalt catalysts supported on Al2O3, SiO2, and TiO2 was investigated using a closed system filled with hydrogen gas. Effects of support and metal loading on the rate of reduction were also discussed. The activation energy of reduction increased in the following order: Co/TiO2<Co/Al2O3<Co/SiO2. For different metal loadings, it was found that the catalyst with the higher loading was more readily reducible than that with the lower metal loading. This was confirmed using the results from measurements of particle size, amount of CO adsorbed and activity.

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References

  1. F.N. Hill and P.W. Selwood, J. Am. Chem. Soc. 71 (1949) 2522.

    Google Scholar 

  2. V.C.F. Holm and A. Clark, J. Catal. 11 (1968) 305.

    Google Scholar 

  3. M. Boudart,Kinetics of Chemical Processes (Prentice-Hall, Englewood Cliffs, 1968).

    Google Scholar 

  4. J.M. Zowtiak and C.H. Bartholomew, J. Catal. 83 (1983) 107.

    Google Scholar 

  5. R.C. Reuel and C.H. Bartholomew, J. Catal. 85 (1984) 63.

    Google Scholar 

  6. B.A. Sexton, A.E. Hughes and T.W. Turney, J. Catal. 97 (1986) 390.

    Google Scholar 

  7. C.R.F. Lund and J.A. Dumesic, J. Phys. Chem. 85 (1982) 3175.

    Google Scholar 

  8. J.W. Niemantsverdriet, A.M. Van Der Kraan and W.N. Delgass, J. Catal. 89 (1984) 138.

    Google Scholar 

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Choi, JG. Reduction of supported cobalt catalysts by hydrogen. Catal Lett 35, 291–296 (1995). https://doi.org/10.1007/BF00807185

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  • DOI: https://doi.org/10.1007/BF00807185

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