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Enantiomere und diastereomere 2-Methoxymethyl-pyrrolidin-1-dithiocarbonsäureester

Enantiomeric and diastereomeric esters of 2-methoxymethyl-pyrrolidine-1-dithiocarboxylic acids

  • Organische Chemie Und Biochemie
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Summary

Formation of the 2-methoxymethyl-pyrrolidine-1-dithiocarboxylates2–4 and alkylation of2 and3 were studied. Enantiomeric and diastereomeric derivatives of4, the preparation of diastereomeric mixtures of4 by alkylation of3 in the presence of strong bases, and formation of6 by phase transfer alkylation of2 are described. The two enantiomers of 2-(4-bromophenyl)-2-oxo-ethyl 2-methoxymethylpyrrolidine-1-dithiocarboxylate2 have been characterized by X-ray analysis.

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Authors and Affiliations

  1. Institut für Organische Chemie, Martin-Luther-Universität Halle-Wittenberg, D-06120, Halle, Bundesrepublik Deutschland

    W. Dölling, I. Hocke & P. Verjus

  2. Institut für Physikalische Chemie, Martin-Luther-Universität Halle-Wittenberg, D-06108, Halle, Bundesrepublik Deutschland

    M. Biedermann & H. Hartung

Authors
  1. W. Dölling
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  2. I. Hocke
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  3. P. Verjus
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  4. M. Biedermann
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  5. H. Hartung
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Verstorben am 22. Juni 1996

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Dölling, W., Hocke, I., Verjus, P. et al. Enantiomere und diastereomere 2-Methoxymethyl-pyrrolidin-1-dithiocarbonsäureester. Monatsh Chem 128, 881–891 (1997). https://doi.org/10.1007/BF00807097

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  • DOI: https://doi.org/10.1007/BF00807097

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