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Mannich bases as model compounds for intramolecular hydrogen bonding I. Solid state structures and molecular calculations

Mannich-Basen als Modelle für Intramolekulare Wasserstoffbrücken, 1. Mitt. Festkörperstrukturen und Molekülrechnungen

  • Anorganische Und Physikalische Chemie
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Summary

A survey of the structures and the properties of the hydrogen bonds inortho-aminomethylphenols and -naphthols in the solid state is presented. The results are compared with molecular structure calculations. The solid state complexes can exist in the molecular or in zwitterionic form. In the last case, only intermolecular hydrogen bonds forming cyclic dimers or linear chains were detected.

Zusammenfassung

Eine Übersicht über Strukturen und Eigenschaften von Wasserstoffbrücken inortho-Aminomethylphenolen und -naphtholen wird präsentiert. Die Ergebnisse werden mit Molekülrechnungen verglichen. Im Festkörper existieren diese Verbindungen in neutraler oder in zwitterionischer Form. Für den zweiten Fall können nur intermolekulare Wasserstoffbrücken nachgewiesen werden, und zwar in Dimeren oder in linearen Ketten.

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Authors and Affiliations

  1. Institute of Chemistry, University of Wroclaw, PL-50383, Wroclaw, Poland

    A. Koll

  2. Institut für Theoretische Chemie und Strahlenchemie, Universität Wien, A-1090, Wien, Austria

    P. Wolschann

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  1. A. Koll
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  2. P. Wolschann
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Koll, A., Wolschann, P. Mannich bases as model compounds for intramolecular hydrogen bonding I. Solid state structures and molecular calculations. Monatsh Chem 127, 475–486 (1996). https://doi.org/10.1007/BF00807072

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