Abstract
An equation for the phenomenon of competetive adsorption from binary liquid mixtures onto solids has been derived using the kinetic approach. In this equation the difference of the molecular sizes, the non-ideality of both bulk surface phases, and the energetic heterogeneity of the solid surface have been taken into account.
Zusammenfassung
Auf Grund kinetischer Erwägungen wurde eine Gleichung, die die Konkurrenzadsorption aus binären Lösungsmittelgemischen an den Oberflächen fester Körper beschreibt, aufgestellt. In der Gleichung wurde der Größenunterschied der Teilchen, die Nichtidealität der Lösung in der Volumen- und Oberflächenphase, sowie die energetische Heterogenität der Oberfläche des festen Körpers berücksichtigt.
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Dąbrowski, A. Theoretical studies on the adsorption from non-ideal binary liquid mixtures on heterogeneous surfaces involving difference in molecular sizes of components. Monatsh Chem 114, 875–890 (1983). https://doi.org/10.1007/BF00799949
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DOI: https://doi.org/10.1007/BF00799949