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Diastereomeric Oxathia[n](1,1′)ferrocenophanes

Diastereomere oxathia[n](1,1′)ferrocenophane

  • Organische Chemie Und Biochemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Novel oxathiaferrocenophanes have been synthesized by the reaction of 1,1′-bis(hydroxymethyl)ferrocene with dithiols bearing oxygen in chains. The reactions of 1,1′-bis(α-hydroxyethyl)ferrocenes with dithiols afforded mixtures of diastereomeric products from which pure stereoisomers were isolated and characterized. Some aspects concerning a stereochemical course of the reactions described are discussed.

Zusammenfassung

Neue Oxathiaferrocenophane wurden durch Umsetzung von 1,1′-Bis(hydroxymethyl)ferrocen mit Dithiolen dargestellt, welche Sauerstoff in den Alkylketten enthalten. Die Reaktion von 1,1′-Bis(α-hydroxyethyl)ferrocenen mit Dithiolen führte zu Mischungen von Diastereomeren, aus welchen reine Stereoisomere isoliert und charakterisiert wurden. Einige Aspekte des stereochemischen Verlaufes dieser Reaktionen werden diskutiert.

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Authors and Affiliations

  1. Department of Organic Synthesis, Silesian University, 40006, Katowice, Poland

    Bronisław Czech & Aleksander Ratajczak

  2. Regional Laboratory of Physicochemical Analysis and Structural Research, Jagiellonian University, 30060, Cracow, Poland

    Krzysztof Nagraba

Authors
  1. Bronisław Czech
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  2. Aleksander Ratajczak
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  3. Krzysztof Nagraba
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Czech, B., Ratajczak, A. & Nagraba, K. Diastereomeric Oxathia[n](1,1′)ferrocenophanes. Monatsh Chem 113, 965–972 (1982). https://doi.org/10.1007/BF00799237

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  • DOI: https://doi.org/10.1007/BF00799237

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