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Application of a bilayer adsorption model for explaining the adsorption of esters fromn-heptane and benzene on silica gel

Die Anwendung eines Zweischicht-Adsorptionsmodells zum Verständnis der Adsorption von Estern ausn-Heptan- und Benzollösungen auf Kieselgel

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The adsorption isotherms of methyl, ethyl,n-propyl andn-butyl acetates from benzene andn-heptane on silica gel have been measured at 298 K. A bilayer model of surface phase has been used to interpret these experimental data. It has been shown that the chain length of the hydrocarbon part of the ester and the solvent affinity to the adsorbent influence the structure of the surface phase. Moreover, this structure is also determined by energetic heterogeneity of the adsorbent surface.

Zusammenfassung

Es wurden die Adsorptionsisothermen der Methyl-, Ethyl-,n-Propyl undn-Butylacetate in Benzol undn-Heptanlösungen auf Kieselgel bei 298 K gemessen. Zur Interpretation der experimentellen Daten ist ein Zweischicht-Modell für die Oberflächenphase benutzt worden. Es wurde gezeigt, daß die Länge der Esterkohlenwasserstoffkette und die Aktivität des Lösungsmittels Einfluß auf die Struktur der Oberflächenform haben. Außerdem ist diese Struktur durch energetische Inhomogenität der Adsorbensoberfläche bestimmt.

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References

  1. Mills A. K., Hockey J. A., J. Chem. Soc. Faraday I12, 2384 (1975).

    Google Scholar 

  2. Mills A. K., Hockey J. A., J. Chem. Soc. Faraday I12, 2392 (1975).

    Google Scholar 

  3. Mills A. K., Hockey J. A., J. Chem. Soc. Faraday I12, 2398 (1975).

    Google Scholar 

  4. Armistad C. G., Tyler A. J., Hockey J. A., Trans. Faraday Soc.67, 493 (1971).

    Google Scholar 

  5. Armistad C. G., Tyler A. J., Hockey J. A., Trans. Faraday Soc.67, 500 (1971).

    Google Scholar 

  6. Ościk J., Goworek J., Polish J. Chem.52, 1781 (1978).

    Google Scholar 

  7. Jaroniec M., Ościk J., Deryło A., Monatsh. Chem.112, 175 (1981).

    Google Scholar 

  8. Jaroniec M., Ościk J., Deryło A., Kusak R., Czarniecki J., Monatsh. Chem.113, 29 (1982).

    Google Scholar 

  9. Keibal V. L., Kiselev A. V., Savinov I. M., Khudiakov V. L., Shcherbakova K. D., Yaschin Y. I., Zhur. Fiz. Khim.41, 2234 (1967).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, MCS University, PL-20031, Lublin, Poland

    Jacek Goworek, Andrzej Dąbrowski, Mieczysław Jaroniec & Jerzy Garbacz

  2. Institute of Chemistry, N. Copernicus University, PL-87100, Toruń, Poland

    Jerzy Garbacz

Authors
  1. Jacek Goworek
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  2. Andrzej Dąbrowski
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  3. Mieczysław Jaroniec
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  4. Jerzy Garbacz
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Goworek, J., Dąbrowski, A., Jaroniec, M. et al. Application of a bilayer adsorption model for explaining the adsorption of esters fromn-heptane and benzene on silica gel. Monatsh Chem 113, 925–932 (1982). https://doi.org/10.1007/BF00799233

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  • DOI: https://doi.org/10.1007/BF00799233

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