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Zum Kristallisations- und Schmelzverhalten von Auripigment und den strukturanalogen Verbindungen Claudetit und Arsenselenid

Crystallization and melting behaviour of orpiment and the structural analog compounds claudetite and arsenic selenide

  • Anorganische Und Physikalische Chemie
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Abstract

The rates of homogeneous nucleation of orpiment (As2S3), claudetite (As2O3) and arsenic selenide (As2Se3) in their undercooled melts are much lower than the calculated values. From the slow nucleation rates results the extremely low tendency towards crystallization of the pure undercooled melts. By seeding crystals or under conditions favouring a heterogeneous nucleation, crystalline As2S3 and As2Se3 were obtained from the melt. Orpiment shows a retarded melting behaviour and can be superheated beyond its melting point of 591 K.

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Authors and Affiliations

  1. Sektion Chemie, Friedrich-Schiller-Universität Jena, DDR-6900, Jena, Deutsche Demokratische Republik

    Bernd Voigt & Brigitte Jacob

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  1. Bernd Voigt
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  2. Brigitte Jacob
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Voigt, B., Jacob, B. Zum Kristallisations- und Schmelzverhalten von Auripigment und den strukturanalogen Verbindungen Claudetit und Arsenselenid. Monatsh Chem 113, 895–906 (1982). https://doi.org/10.1007/BF00799230

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  • DOI: https://doi.org/10.1007/BF00799230

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