Abstract
Cathodic reduction of non-terminal vinylazides on Hg cathodes in the presence of electrophiles gives reasonable yields of N-acylated enamines in an electrochemically totally irreversible reaction. In the presence of added H-donors rather high selectivity for formation of saturated amides is achieveable. The influence of reaction conditions on product distribution is discussed.
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Knittel, D. Kathodische Reduktion von α-Azidostyrolen. Monatsh Chem 115, 523–531 (1984). https://doi.org/10.1007/BF00799159
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DOI: https://doi.org/10.1007/BF00799159