Abstract
Two cyano complexes of the type [R 3S]2 [Pd(CN)4] (R 3S+=Me 3S+,Ph 3S+ cations) were prepared. The identity of the obtained samples was verified by chemical analysis and investigated by IR-spectroscopy. Thev CN stretching frequencies of the complexes were compared with similar frequencies of the corresponding alkaline cyano complex. The thermal decomposition of the compounds was examined.
This is a preview of subscription content, log in via an institution to check access.
Literatur
Emeléus H. J.,Heal H. G., J. Chem. Soc.1946, 1126.
Wildi B. S., Taylor S. W., Potratz H. A., J. Amer. Chem. Soc.73, 1965 (1951).
Sharpe A. G., The Chemistry of Cyano Complexes of Transition Metals. New York: Academic Press 1976.
Györyová K., Mohai B., Z. Anorg. Allg. Chem.492, 175 (1982).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Györyová, K., Skoršepa, J. & Chomič, J. Synthese von Trimethyl- und Triphenylsulfonium-Cyanometallaten. Monatsh Chem 114, 1137–1139 (1983). https://doi.org/10.1007/BF00799037
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00799037