Abstract
The title compounds3 can be prepared either from the iodonium-ylides1 or from the chlorocompounds4. On treatment with hydrochloric acid the thiophanium-ylides3 C undergo ring cleavage to the chlorobutylsulfides5, also formed from4 and thiophane. The dimethylsulfonium-ylide8 is derived from activatedDMSO and7 b. TheOrtoleva-King reaction is discussed as an alternative method for preparing pyridiniumylides.
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Kappe, T., Korbuly, G. & Pongratz, E. Ylide von Heterocyclen, IV. Sulfonium- und Pyridinium-Ylide des Cumarins und des 2-Chinolons. Monatsh Chem 114, 303–315 (1983). https://doi.org/10.1007/BF00798953
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DOI: https://doi.org/10.1007/BF00798953