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Untersuchungen über das Gleichgewicht des Hg2+-Hg 2+2 -Hg-Systems in konzentrierten Perchloratlösungen

Study of the equilibrium of the Hg2+-Hg 2+2 -Hg system in concentrated perchlorate solutions

  • Anorganische Und Physikalische Chemie
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Abstract

The formal potentials of the Hg2+/Hg 2+2 , Hg 2+2 /Hg and Hg2+/Hg redox couples and the apparent equilibrium constants of the reaction Hg2+ + Hg ∝ Hg 2+2 in conc. aqueous solutions of Mg(ClO4)2 and Ca(ClO4)2 have been determined from emf measurements performed using cells with liquid junction. Based on these data, the hydration numbers of the Hg2+ and Hg 2+2 ions were estimated.

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Authors and Affiliations

  1. Institut für Chemie, Pädagogische Hochschule, PL-25020, Kielce, Polen

    Ewa Malyszko & Jan Malyszko

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  1. Ewa Malyszko
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  2. Jan Malyszko
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Malyszko, E., Malyszko, J. Untersuchungen über das Gleichgewicht des Hg2+-Hg 2+2 -Hg-Systems in konzentrierten Perchloratlösungen. Monatsh Chem 114, 547–558 (1983). https://doi.org/10.1007/BF00798609

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  • DOI: https://doi.org/10.1007/BF00798609

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