Abstract
The solid stateRaman spectra (300−50 cm−1) of lithium hydrogen oxalate monohydrate have been investigated for four isotopically substituted compounds,6LiHC2O4·H2O,7LiHC2O4·H2O,6LiDC2O4·D2O and7LiDC2O4·D2O. The observed spectral data have been discussed on the basis of the factor group analysis by considering the H/D and6Li/7Li isotope effects on the fundamental lattice vibrations.
Zusammenfassung
Es wurden vier isotopensubstituierte Verbindungen (6LiHC2O4·H2O,7LiHC2O4·H2O,6LiDC2O4·D2O und7LiDC2O4·D2O) mittelsRaman-Festkörper-Spektroskopie im Bereich von 300−50 cm−1 untersucht. Die ermittelten Daten werden auf Basis der Faktorengruppenanalyse unter Beachtung der H/D- und6Li/7Li-Isotopeneffekte diskutiert.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Yoshida I. V. P., Hase Y., Appl. Spectrosc.32, 590 (1978).
Hase Y., Yoshida I. V. P., Spectrochim. Acta35A, 379 (1979).
Yoshida I. V. P., Hase Y., Spectrosc. Lett.12, 409 (1979).
Hase Y., Yoshida I. V. P., Chem. Phys. Lett.65, 46 (1979).
Hase Y., Inorg. Nucl. Chem. Lett.16, 159 (1980).
Hase Y., Yoshida I. V. P., Monatsh. Chem.111, 1265 (1980).
Hase Y., Monatsh. Chem.112, 73 (1981).
Hase Y., Spectrochim. Acta37 A, 275 (1981).
Hase Y., Monatsh. Chem.113, 409 (1982).
De Villepin J., Novak A., J. Mol. Struct.30, 255 (1976).
Follner H., Z. anorg. allg. Chem.373, 198 (1970).
Thomas J. O., Acta Crystallogr.B28, 2037 (1972).
De Villepin J., Novak A., Spectrochim. Acta27 A, 1259 (1971).
De Villepin J., Novak A., Spectrosc. Lett.4, 1 (1971).
Eriksson A., Lindgren J., J. Mol. Struct.48, 417 (1978).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hase, Y. Low wavenumberRaman bands (300−50cm−1) for four isotopically substituted lithium hydrogen oxalate monohydrates LiXC2O4·X 2O. Monatsh Chem 114, 541–546 (1983). https://doi.org/10.1007/BF00798608
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00798608