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Azide mit zwei verschiedenen Metallatomen

Azides containing two different metal atoms

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Crystal structures of azides containing two different metal atoms are discussed. Elements with higher electronegativity have the greatest influence on the structures. They form finite or infinite metal azide complexes, the degree of covalent binding betweenM(II) and azide groups raises with increasing ionisation potential of the metal, the stability of complex azides is not influenced seriously thereof. The arrangement ofM(I)-ions is influenced to a large extent by the stereochemistry. The azide groups are essentially asymmetrical with N-N-distances between 1.10 and 1.28 Å, the mean distance is 1.18 (3) Å. Azide groups are slightly bent [N-N-N=177 (5)°] and are always coordinated to several metal atoms. Frequently the central nitrogen atoms of azide groups are located closer toM(I)-ions than terminal nitrogens. Some complex azides contain water which is situated beside the azide groups within the coordination polyhedra.

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Authors and Affiliations

  1. Abteilung für Strukturforschung, Institut für Physikalische und Theoretische Chemie, Technische Universität Graz, A-8010, Graz, Österreich

    Harald Krischner

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  1. Harald Krischner
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Krischner, H. Azide mit zwei verschiedenen Metallatomen. Monatsh Chem 116, 189–202 (1985). https://doi.org/10.1007/BF00798454

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  • DOI: https://doi.org/10.1007/BF00798454

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