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Ferrocene derivatives, part 6757Fe-NMR spectroscopy of ferrocenes

57Fe-Kernresonanzspektren von Ferrocenderivaten. Ferrocenderivate 67

  • Organische Chemie Und Biochemie
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Abstract

57Fe NMR-spectra of 28 mono and disubstituted ferrocenes with a natural abundance of57Fe have been measured relative to internal ferrocene. Most of the resonances appear at the high frequency side. The shielding influence of the various substituents is discussed qualitatively.57Fe shifts are very sensitive to ring tilting as occurring in [3]ferrocenophanes.

Zusammenfassung

57Fe-NMR-Signale von 28 mono- und disubstituierten Ferrocenen mit natürlicher Häufigkeit an57Fe wurden gegen Ferrocen als innerem Standard gemessen. Die meisten Resonanzen sind zu höherer Frequenz verschoben. Die57Fe-Verschiebung reagiert sehr empfindlich auf Ringneigung, wie an [3]Ferrocenophanen gezeigt wurde. Substituenteneinflüsse auf die Verschiebung werden qualitativ diskutiert.

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References

  1. Part 66:Paulus H., Schlögl K., Weissensteiner W., Monatsh. Chem.113, 767 (1982).

    Google Scholar 

  2. Haslinger E.,Robien W.,Schlögl K.,Weissensteiner W., J. Organometal. Chem.218, C 11 (1981).

  3. Koridze A. A.,Petrovskii P. V.,Gubin S. P.,Fedin E. I., J. Organometal. Chem.93, C 26 (1975).

  4. Koridze A. A.,Petrovskii P. V.,Gubin S. P.,Fedin E. I.,Lutsenko A. I.,Amitin I. P.,Okulevich P. O., Izv. Akad. Nauk SSSR, Ser. Khim.1975, 1675; C. A.83, 155202 e (1975).

  5. Koridze A. A., Astachowa H. M., Petrovskii P. W., Lutzenko A. I., Izv. Akad. Nauk SSSR,242, 242 (1978); C. A.90, 5748 t (1979).

    Google Scholar 

  6. Koridze A. A.,Astakhova N. M.,Petrovskii P. V., Contribution at the 4th FECHEM Conference on Organometallic chemistry, Liblice (CSSR), September1, 1982.

  7. Schwenk A., J. Magn. Res.5, 376 (1971).

    Google Scholar 

  8. Sahm W., Schwenk A., Z. Naturf. (A)29, 1763 (1974).

    Google Scholar 

  9. Jenny, T., Philipsborn W. v., Kronenbitter J., Schwenk A., J. Organometal. Chem.205, 211 (1981).

    Google Scholar 

  10. Brevard C., Schimpf R., J. Magn. Res.47, 528 (1982).

    Google Scholar 

  11. See for example:Bublitz D. E., Rinehart K. L., jr., Org. Reactions17, 1 (1969);Schlögl K., Falk H., in: Methodicum Chimicum (Korte F., ed.), Ferrocene, Vol. 8, p. 433. Stuttgart: G. Thieme. 1974; and New York: Academic Press. 1976.

    Google Scholar 

  12. Jones N. D., Marsh R. E., Richards J. H., Acta Cryst.19, 330 (1965).

    Google Scholar 

  13. Haslinger E.,Robien W., unpublished results.

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Author information

Author notes

  1. Kosta Koci

    Present address: Department of Organic Chemistry, University of Tirana, Albania

Authors and Affiliations

  1. Institut für Organische Chemie, Universität Wien, A-1090, Wien, Austria

    Ernst Haslinger, Kosta Koci, Wolfgang Robien & Karl Schlögl

Authors
  1. Ernst Haslinger
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  2. Kosta Koci
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  3. Wolfgang Robien
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  4. Karl Schlögl
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Additional information

For a preliminary communication see Ref.2. Parts of this work were presented at the “NMR-Diskussionstagung” in Dortmund in January 1982 (byE. H.) and at “GERM VI” in Pont à Mousson in March 1982 (byW. R.).

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Haslinger, E., Koci, K., Robien, W. et al. Ferrocene derivatives, part 6757Fe-NMR spectroscopy of ferrocenes. Monatsh Chem 114, 495–499 (1983). https://doi.org/10.1007/BF00798447

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  • DOI: https://doi.org/10.1007/BF00798447

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