Skip to main content
SpringerLink
Log in

Die Kristallstruktur von Dikalium-trikobalt(II)-dihydroxid-trisulfat-dihydrat, K2Co3(OH)2(SO4)3·2H2O

The crystal structure of dipotassium-tricobalt(II)-dihydroxy-trisulfate-dihydrate, K2Co3(OH)2(SO4)3·2H2O

  • Anorganische Und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Crystals of K2Co3(OH)2(SO4)3·2H2O were synthesized under hydrothermal conditions. The crystal structure [a=17.945 (4) Å,b=7.557 (2) Å,c=9.760 (3) Å, space group Cmc21,Z=4] was determined by direct methods and refined with single crystal X-ray data. The H atoms were located byFourier syntheses. Their structural parameters were refined, too. The finalR-values areR=0.025 andR w =0.028 (w=1/σ) for 612 reflections withF 0>3 σ (F 0). Both Co(II) atoms are octahedral six coordinated and form zigzag chains running parallel [001]. These chains are connected via sulfate groups to built up sheets parallel (100). The KO9 polyhedron and one of the four hydrogen bonds link these sheets.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. Dubler E., Oswald H. R., Naturwiss.56, 327 (1969).

    Google Scholar 

  2. Dubler E., Oswald H. R., J. Appl. Cryst.3, 175 (1970)

    Google Scholar 

  3. International Tables for X-ray Crystallography, Vol. IV. Birmingham: The Kynoch Press. 1974.

  4. Zachariasen W. H., Acta Cryst.23, 558 (1967).

    Google Scholar 

  5. Shannon R. D., Acta Cryst.A32, 751 (1976).

    Google Scholar 

  6. Cocco G., Fanfani L., Zanazzi P. F., Handbook of Geochemistry II-2, 19/A. Berlin-Heidelberg-New York: Springer. 1972.

    Google Scholar 

  7. Payan F., Haser R., Acta Cryst.B32, 1875 (1976).

    Google Scholar 

  8. Krogh-Moe J., Acta Cryst.18, 1088 (1965).

    Google Scholar 

  9. Srikanta S., Sequeira A., Chidambaram R., Acta Cryst.B24, 1176 (1968)

    Google Scholar 

  10. Anderson J. B., Kostiner E., Miller M. C., Rea J. R., J. Solid State Chem.14, 372 (1975).

    Google Scholar 

  11. Anderson J. B., Kostiner E., Ruszala F. A., Inorg. Chem.15, 2744 (1976).

    Google Scholar 

  12. Nord A. G., Stefanidis T., Z. Krist.153, 141 (1980).

    Google Scholar 

  13. Gopal R., Rutherford J. S., Robertson B. E., J. Solid State Chem.32, 29 (1980).

    Google Scholar 

  14. Dubler E., Oswald H. R., Helv. Chim. Acta54, 1621 (1971).

    Google Scholar 

  15. Ruszala F. A., Anderson J. B., Kostiner E., Inorg. Chem.16, 2417 (1977).

    Google Scholar 

  16. Baur W. H., Acta Cryst.17, 1361 (1964).

    Google Scholar 

  17. Wuensch B. J., Handbook of Geochemistry II-2, 16/A. Berlin-Heidelberg-New York: Springer. 1972.

    Google Scholar 

  18. Brown I. D., Wu K. K., Acta Cryst.B32, 1957 (1976).

    Google Scholar 

  19. Chiari G., Ferraris G., Acta Cryst.B38, 2331 (1982).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Mineralogie und Kristallographie, Universität Wien, A-1010, Wien, Österreich

    H. Effenberger

  2. Stoe & Cie Ges.m.b.H., D-6100, Darmstadt, Bundesrepublik Deutschland

    H. Langhof

Authors
  1. H. Effenberger
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Langhof
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Effenberger, H., Langhof, H. Die Kristallstruktur von Dikalium-trikobalt(II)-dihydroxid-trisulfat-dihydrat, K2Co3(OH)2(SO4)3·2H2O. Monatsh Chem 115, 165–177 (1984). https://doi.org/10.1007/BF00798407

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00798407

Keywords

Search

Navigation