Abstract
PhPCp 2 could be prepared by the reaction ofPhPCl2 withCpNa. The metallation ofPhPCp 2 withn-BuLi and the following reaction with TiCl4 led to the first P-bridged [1]titanocenophane. Structural assignments of this compound could be made on the base of its1H-NMR spectrum.
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Köpf, H., Klouras, N. Das erste [1]Titanocenophan mit Phosphor-Brücke. Monatsh Chem 114, 243–247 (1983). https://doi.org/10.1007/BF00798327
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DOI: https://doi.org/10.1007/BF00798327