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Factors influencing asymmetric induction in the addition of thioacids to 2-cyclohexenone

Die asymmetrische Induktion beeinflussende Faktoren bei der Addition von Thiocarbonsäuren an 2-Cyclohexen (Kurz Mitteilung)

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  • Organische Chemie Und Biochemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The enantiomeric excess of the product of conjugate addition of a thioacid to 2-cyclohexenone can be increased by proper choice of the thioacid structure, concentration and modification of the structure of the chiral catalyst.

Zusammenfassung

Es konnte der enantiomere Überschuß in den Produkten aus der Addition von Thiocarbonsäuren an 2-Cyclohexen durch die Auswahl geeigneter Thiocarbonsäuren, deren Konzentration und durch Modifikation am chiralen Katalysator gesteigert werden.

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References

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Brzostowska, M., Gawroński, J. Factors influencing asymmetric induction in the addition of thioacids to 2-cyclohexenone. Monatsh Chem 115, 1373–1376 (1984). https://doi.org/10.1007/BF00798316

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  • DOI: https://doi.org/10.1007/BF00798316

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