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Stereoselective oxidative addition of benzenethiol to idene in the presence of ovoalbumin

Stereoselektive oxydative Anlagerung von Thiophenol an Inden in Gegenwart von Ovoalbumin (Kurze Mitteilung)

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  • Organische Chemie Und Biochemie
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Abstract

The oxidative addition of benzenethiol to indene in the presence of ovoalbumin produces only one isomer on the surface of the protein,trans-anti-2-phenylsulfinyl-1-indanol. This reaction may be considered as a biomimetic model of detoxification of certain hydrocarbons by the liver.

Zusammenfassung

Durch die oxydative Anlagerung von Thiophenol an Inden in Gegenwart von Ovoalbumin bildet sich nur ein Isomer an der Oberfläche des Proteins, dastrans-anti-2-Phenylsulfinyl-1-Indanol. Diese Reaktion kann als ein biomimetisches Modell der Entgiftung von gewissen Kohlenwasserstoffen durch die Leber betrachtet werden.

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Baeza, J., Freer, J. & Palma, G. Stereoselective oxidative addition of benzenethiol to idene in the presence of ovoalbumin. Monatsh Chem 115, 1369–1371 (1984). https://doi.org/10.1007/BF00798315

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  • DOI: https://doi.org/10.1007/BF00798315

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