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Hydrogen bonding and tautomeric equilibria of complexes of pyridine with various proton donors a nitrogen-15 nuclear magnetic resonance study

Wasserstoffbrückenbindung und Protonenübertragung in Komplexen zwischen Pyridin und verschiedenen Protonendonatoren. Eine Stickstoff-15-NMR-Untersuchung

  • Organische Chemie Und Biochemie
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Abstract

The15N-NMR-spectra of pyridine in presence of several proton donors are given. The concentration dependence of the chemical shifts can be described formally by a two step mechanism including proton transfer.

Zusammenfassung

Die15N-NMR-Spektren von Pyridin mit einigen Protonendonatoren sind angegeben. Die Konzentrationsabhängigkeit der chemischen Verschiebung kann formal durch ein zweistufiges Gleichgewicht, welches einen Protonenübergang beinhaltet, beschrieben werden.

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Authors and Affiliations

  1. Institut für Organische Chemie, Universität Wien, A-1090, Wien, Austria

    Ernst Haslinger & Wolfgang Robien

  2. Institut für Theoretische Chemie und Strahlenchemie, Universität Wien, A-1090, Wien, Austria

    Margit Schlederer & Peter Wolschann

Authors
  1. Ernst Haslinger
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  2. Margit Schlederer
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  3. Wolfgang Robien
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  4. Peter Wolschann
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Haslinger, E., Schlederer, M., Robien, W. et al. Hydrogen bonding and tautomeric equilibria of complexes of pyridine with various proton donors a nitrogen-15 nuclear magnetic resonance study. Monatsh Chem 115, 1345–1351 (1984). https://doi.org/10.1007/BF00798313

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  • DOI: https://doi.org/10.1007/BF00798313

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