Conclusions
-
1.
The method of electron beam vaporization of rods prepared from synthetic mullite can be successfully used for the deposition of vitreous aluminum silicate coatings with a composition close to that of mullite on metallic surfaces.
-
2.
The method of infrared spectroscopy makes it possible to determine qualitatively the phase composition of such a coating, assess the degree of mullitization of deposited films, and detect in them any uncombined aluminum and silicon oxides.
-
3.
The temperature ranges of compatibility of 0.35-μ thick aluminum silicate coatings with various metallic substrates have been determined.
-
4.
The spectra of films deposited on the metals investigated show an extra band in the 1500-1400 cm−1 range, which is similar to the bands found in the spectra of silica and alumina films in the 1300-1260 and 1000-960cm−1 ranges, respectively.
Similar content being viewed by others
Literature cited
I. Williams, W. Sinclair, and S. Koonce, J. Am. Ceram. Soc.,46, 163 (1963).
W. Pliskin, D. Kerr, and J. Perry, in: Physics of Thin Films [Russian translation], Vol. 4, Mir, Moscow (1970), p. 304.
R. Kieffer and P. Schwarzkopf, Hartstoffe and Hartmetalle, Springer (1953).
V. M. Grosheva, D. M. Karpinos, and V. M. Panasevich, Synthetic Mullite and Materials Based on It [in Russian], Tekhnika, Kiev (1971).
I. I. Plyusnina, Infrared Spectra of Silicates [in Russian], Izd-vo MGU, Moscow (1967).
P. Tarte, Silicates Ind.,28, 345 (1963).
A. N. Lazarev, Vibration Spectra and Structure of Silicates [in Russian], Nauka, Leningrad (1968).
S. Francis and A. Ellison, J. Opt. Soc. Am.,49, 131 (1959).
D. M. Karpinos, S. P. Listovnichaya, and V. Ya. Aivazov, Pribory i Tekh. Éksperim.,6, 191 (1971).
D. M. Karpinos and S. P. Listovnichaya, Poroshkovaya Met., No. 12, 69 (1971).
D. M. Karpinos, S. P. Listovnichaya, and V. Ya. Aivazov, Poroshkovaya Met. (1973).
D. M. Karpinos, V. Ya. Aivazov, and S. P. Listovnichaya, Poroshkovaya Met. (1973).
D. M. Karpinos, V. G. Zil'berberg, et al., Ogneupory, No. 11, 47 (1971).
V. P. Belevskii and V. M. Koptenko, Pribory i Tekh. Éksperim.,4, 146 (1969).
L. Holland, Thin Film Microelectronics, Wiley (1966).
W. Weiskirchner, Z. Naturforsch.,6a, 509 (1951).
G. Pedan, L. Levitova, and I. Skorobogatova, In: Theoretical and Technological Investigations in the Field of Refractories [in Russian], No. 5, 300 (1965).
I. M. Kuznetsov, Dep. 1029-69, Infrared Spectra of Dehydrated Kaolin and Its Conversion Products [in Russian].
W. Pliskin, P. Davids, et al., J. Res. Develop.,11, 461 (1967).
M. Miller, Solid State Electron.,7, No. 4, 391 (1968).
R. Hannah, Appl. Spectry.,17, 23 (1963).
Author information
Authors and Affiliations
Additional information
Translated from Poroshkovaya Metallurgiya, No. 9 (129), pp. 30–34, September, 1973.
Rights and permissions
About this article
Cite this article
Aivazov, V.Y., Grosheva, V.M., Karpinos, D.M. et al. Reaction of an aluminum silicate coating with some metals. Powder Metall Met Ceram 12, 715–718 (1973). https://doi.org/10.1007/BF00793979
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00793979