Conclusions
Comminution of carbides in various media which do not prevent the well-developed surfaces of their particles from coming into contact with water and oxygen leads to surface oxidation of these particles. This is reflected in the chemical composition of carbides, which almost continually changes during sintering in the usual temperature range, right up to 2200‡C, and in the densification kinetics and properties of carbide-base materials. Because of the instability of oxycarbides of the Group V metals in a vacuum at these temperatures, with the carbides “MevC” (NbC and TaC) the surface oxidation experienced by their particles during milling in certain dispersing media may have an activating effect on the sintering process and shift the composition of the carbides toward the lower limits of their homogeneity ranges.
Similar content being viewed by others
Literature cited
A. I. Avgustinik, G. V. Drozdetskaya, and S. S. Ordan'yan, Poroshk. Met., No. 6 (1967).
A. I. Avgustinik, G. V. Drozdetskaya, and S. S. Ordan'yan, Izv. Vyssh. Uchebn. Zaved., Khim. i Khim. Tekhnol.,14, No. 11, 1717 (1971).
E. Storms, Refractory Carbides, Academic Press (1967).
S. S. Ordan'yan, K. N. Egorov, and I. A. Matusov, Poroshk. Met., No. 4 (1970).
B. J. Warren, in: Advances in Metal Physics [Russian translation], Vol. 5, Moscow (1963), p. 172.
G. V. Drozdetskaya, Candidate's Dissertation, Leningrad (1968).
G. V. Zakharova, I. A. Popov, L. P. Zhorova, and B. V. Fedin, Niobium and Its Alloys [in Russian], Metallurgizdat, Moscow (1961), p. 20.
S. S. Ordan'yan, L. V. Kudryasheva, and A. I. Avgustinik, Poroshk. Met., No. 8 (1968).
Author information
Authors and Affiliations
Additional information
Translated from Poroshkovaya Metallurgiya, No. 2(170), pp. 23–28, February, 1977.
Rights and permissions
About this article
Cite this article
Ordan'yan, S.S., Savel'ev, G.A., Kravchik, A.E. et al. Effect of milling in various media on the composition and some properties of niobium carbide. Powder Metall Met Ceram 16, 100–103 (1977). https://doi.org/10.1007/BF00793782
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00793782