Summary
Some aspects of “classical” thermodynamics of phase transformations are discussed. Then typical solid state transformations as the displacive and diffusional transformation in metals are explained. A general formulation of the Gibbs free energy is presented including all energy terms required. Based on the “classical” nucleation, the “triggering-off” and the “dissipation” condition, various transformation conditions are formulated taking into account the elasto-plastic deformation of both phases. Transformation conditions presented in the literature over the last 40 years are reviewed and compared to the transformation conditions derived here. The transformation conditions for a spherical region growing under a certain volume change in an elasto-plastic matrix are studied as an example. The relevant analytical expressions are presented and discussed.
Übersicht
Einige Aspekte der „klassischen” Thermodynamik von Phasenumwandlungen werden behandelt. In der Folge werden typische Festkörperumwandlungen wie die displazive und die diffusive Umwandlung in Metallen erörtert. In allgemeiner Formulierung wird die Gibbs Energie unter Berücksichtigung aller erforderlichen Energieterme hergeleitet Basierend auf der klassischen Keimentwicklungsbedingung, einer Formulierung über das Wachstum von Keimen und einem auf der Dissipationsleistung beruhenden Konzept werden verschiedene Umwandlungsbedingungen hergeleitet. Dabei wird in beiden Phasen elasto-plastisches Materialverhalten vorausgesetzt. Die hier formulierten Umwandlungsbedingungen werden mit einigen der in den letzten 40 Jahren publizierten Beziehungen verglichen und bewertet. In einem Beispiel werden diese Bedingungen für eine in einer elasto-plastischen Matrix wachsende Kugel bei einer umwandlungsbedingten Volumsdehnung angewandt. Analytische Ausdrücke werden präsentiert und näher erläutert.
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Fischer, F.D., Berveiller, M., Tanaka, K. et al. Continuum mechanical aspects of phase transformations in solids. Arch. Appl. Mech. 64, 54–85 (1994). https://doi.org/10.1007/BF00789099
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DOI: https://doi.org/10.1007/BF00789099