Catalysis Letters

, Volume 18, Issue 3, pp 261–264 | Cite as

Unexpected products of the allyldiethylamine hydroformylation homogeneously catalyzed by rhodium complexes

  • Alexandr Jegorov
  • Tomáš Trnka
  • František Tureček
  • Vladimír Hanuš
Article

Abstract

Attempts to carry out the hydroformylation of allyldiethylamine homogeneously catalyzed by rhodium complexes led to unexpected formation of N,N,N′,N′-tetraethyl-1,4-diaminobutane and 4-(diethylamino)-1-butanole as final products. The role of the catalyst on the product formation and the reaction mechanism are briefly discussed.

Keywords

Hydroformylation allylamines N,N, N′, N′-tetraethyl-1,4-diaminobutane 4-(diethylamino)-1-butanole homogeneous catalysis rhodium complexes 

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Copyright information

© J.C. Baltzer AG, Science Publishers 1993

Authors and Affiliations

  • Alexandr Jegorov
    • 1
  • Tomáš Trnka
    • 2
  • František Tureček
    • 3
  • Vladimír Hanuš
    • 4
  1. 1.Research UnitGalena Co.České BudějoviceCzech Republic
  2. 2.Department of Organic ChemistryCharles UniversityPrague 2Czech Republic
  3. 3.Department of Chemistry BG 10University of WashingtonSeattleUSA
  4. 4.Institute of Physical ChemistryCzech Academy of SciencesPragueCzech Republic

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