Abstract
Hydroformylation of hex-1-ene using a water soluble rhodium catalyst HRh(CO)[PPh2(m-C6H4SO3Na)]3 (HRh(CO)(TPPMS)3) (I), gives lower yields whenα-cyclodextrin is added to the biphasic reaction system implying an interaction between the cyclodextrin and rhodium catalyst.
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W.A. Hermann, J.A. Kulpe, J. Kellner, H. Riepl, H. Bahrmann and W. Konkol, Angew. Chem. Int. Ed. Engl. 29 (1990) 391;
E.G. Kunze, Chem. Tech. (1987) 570;
A.F. Borowski, D.J. Cole-Hamilton and G. Wilkinson, Nouv. J. Chemie 2 (1978) 137.
J.T. Lee and H. Alper, Tetrahedron Lett. (1990) 4101;
H.A. Zahalka, K. Januszkiewicz and H. Alper, J. Mol. Cat. 35 (1986) 249;
A. Harada, Y. Hu and S. Takahashi, Chem. Lett. (1986) 2083;
Y. Hu, A. Harada and S. Takahashi, J. Mol. Cat. 60 (1990) L13.
I.T. Horvath, Catal. Lett. 6 (1990) 43.
J.P. Arhancet, M.E. Davis, J.S. Merola and B.E. Hanson, J. Catal. 121 (1990) 327.
M.L. Bender and M. Komiyama,Cyclodextrin chemistry (Springer Verlag, Berlin, 1978).
J. Szejtli,Cyclodextrins and their inclusion complexes (Akademiai Kiado, Budapest, 1982).
P. Escaffre, A. Thorez and P. Kalck, J. Chem. Soc., Chem. Commun. (1987) 146.
H.A. Zahalka and H. Alper, Organometallics 5 (1986) 1909.
A. Benyei and F. Joo, J. Mol. Cat. 58 (1990) 151.
C. Pittman and W. Honnick, J. Org. Chem. 45 (1980) 2132.
H.M. Colquhoun, J.F. Stoddart and D.J. Williams, Angew. Chem. Int. Ed. Engl. 25 (1983) 487.
D.R. Alston, A.M.Z. Slawin, J.F. Stoddart, D.J. Williams and R. Zarzycki, Angew. Chem. Int. Ed. Engl. 27 (1988) 1184.
D.R. Alston, A.M.Z. Slawin, J.F. Stoddart and D.J. Williams, Angew. Chem. Int. Ed. Engl. 24 (1985) 786.
I.T. Horvath, R.V. Kastrup, A.A. Oswald and E.J. Mozeleski, Catal. Lett. 2 (1989) 85.
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Anderson, J.R., Campi, E.M. & Jackson, W.R. Hydroformylation of olefins with water-soluble rhodium catalysts in the presence ofα-cyclodextrin. Catal Lett 9, 55–58 (1991). https://doi.org/10.1007/BF00769081
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DOI: https://doi.org/10.1007/BF00769081