Skip to main content
Log in

The catalytic and electrocatalytic coupling of methane over yttria-stabilized zirconia

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

The catalytic and electrocatalytic oxidation of methane to ethane and ethylene was studied at 900 °C over a gold-supported yttria-stabilized zirconia (Au-YSZ) catalyst. The catalyst was found to be active for C2 formation with C2 selectivities up to 67% and C2 yields up to 15%. Yttria-stabilized zirconia compared favorably to unstabilized yttria-zirconia. Electrochemical oxygen pumping was investigated and found to affect product distribution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J.S. Lee and S.T. Oyama, Catal. Rev.-Sci. Eng. 30 (1988) 249.

    Google Scholar 

  2. K. Otsuka, K. Jinno and A. Morikawa, J. Catal. 100 (1986) 353.

    Google Scholar 

  3. T. Ito and J.H. Lunsford, Nature (London) 314 (1985) 721.

    Google Scholar 

  4. C.G. Vayenas, S. Bebelis and S. Ladas, Nature (London) 343 (1990) 625.

    Google Scholar 

  5. C.G. Vayenas, S. Bebelis, I.V. Yentekakis, P. Tsiakaras and H. Karasali, Plat. Metals Rev. 34 (3) (1990) 122.

    Google Scholar 

  6. K. Otsuka, K. Suga and I. Yamanaka, Catal Lett. 1 (1988) 423.

    Google Scholar 

  7. K. Otsuka, S. Yokoyama and A. Morikawa, Chem. Lett. (1985) 319.

  8. D. Eng, Ph.D. Thesis, Tufts University, 1990.

  9. C.G. Vayenas, S. Bebelis and S. Neophytides, J. Phys. Chem. 92 (1988) 5083.

    Google Scholar 

  10. S. Seimanides, Ph.D. Thesis, Tufts University, 1987.

  11. N.B. Jackson and J.G. Ekerdt, J. Catal. 126 (1990) 31.

    Google Scholar 

  12. C.R.A. Catlow, A.V. Chadwick, G.N. Greaves and L.M. Moroney, J. Am. Ceram. Soc. 69 (1986) 272.

    Google Scholar 

  13. S.J. Korf, J.A. Roos, J.W.H.C. Derksen, J.A. Vreeman, J.G. Van Ommen and J.R.H. Ross, App. Catal. 59 (1990) 291.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Eng, D., Stoukides, M. The catalytic and electrocatalytic coupling of methane over yttria-stabilized zirconia. Catal Lett 9, 47–54 (1991). https://doi.org/10.1007/BF00769080

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00769080

Keywords

Navigation