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Regeneration of platinum-metal-based catalysts with carboxyphosphines as extractants

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Abstract

Separation of platinum-metal-based homogeneous catalysts was achieved by their conversion to complexes of functionalized phosphines of the general formulae R3-n P[(CH2) x CO2H)] n , R = Me, Et, Ph,n = 1, 2, 3,x = 1, 2, and [(HO2CCH2)PCH2]2, followed by extraction of the complexes into aqueous phase. This approach to regeneration of platinum metals from reaction mixtures after carrying out homogeneously catalyzed reactions was demonstrated on 11 examples of various types of reactions with Ru, Rh, Pd, Os, Ir and Pt compounds as catalysts.

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References

  1. R.T. Smith and M.C. Baird, Inorg. Chim. Acta 62 (1982) 135.

    Google Scholar 

  2. F. Joó and Z. Tóth, J. Mol. Catal. 8 (1990) 369.

    Google Scholar 

  3. R.S. Bauer, H. Chung, P.W. Glockner and W. Keim, US Pat. 3,644,563 (19720.

  4. L.H. Pignolet, ed.,Homogeneous Catalysis with Metal Phosphine Complexes (Plenum Press, New York, 1983).

    Google Scholar 

  5. A. Jegorov, J. Podlaha and M. Polievka, Czech Pat. 246734 (1988).

  6. T. Jarolím and J. Podlahová, J. Inorg. Nucl. Chem. 38 (1976) 125.

    Google Scholar 

  7. J. Podlahová, Coll. Czech. Chem. Commun. 43 (1978) 57.

    Google Scholar 

  8. J. Podlahová, Coll. Czech. Chem. Commun. 43 (1978) 3007.

    Google Scholar 

  9. F. Hartl and J. Podlahová, Coll. Czech. Chem. Commun. 49 (1984) 586.

    Google Scholar 

  10. D. Nosková and J. Podlahová, Polyhedron 2 (1983) 349.

    Google Scholar 

  11. M.M. Rauhut, I. Hechenbleikner, H.A. Currier, F.C. Schaeffner and V.P. Wystrach, J. Amer. Chem. Soc. 81 (1959) 1103.

    Google Scholar 

  12. J. Podlahová and J. Podlaha, Coll. Czech. Chem. Commun. 45 (1980) 2049.

    Google Scholar 

  13. N. Ahmad, J.J. Levinson, S.D. Robinson and M.F. Uttley, Inorg. Synth. 15 (1974) 59.

    Google Scholar 

  14. J.A. Osborn and G. Wilkinson, Inorg. Synth. 10 (1967) 67.

    Google Scholar 

  15. R. Cramer, Inorg. Synth. 15 (1974) 14.

    Google Scholar 

  16. K. Vrieze, Inorg. Synth. 11 (1968) 101.

    Google Scholar 

  17. D.M. Adams, P.J. Chandler and R.G. Churchil, J. Chem. Soc. A (1967) 1272.

  18. J.R. Doyle, P.E. Slade and H.B. Jonassen, Inorg. Synth. 6 (1960) 218.

    Google Scholar 

  19. J. Chatt and M.L. Searle, Inorg. Synth. 5 (1957) 210.

    Google Scholar 

  20. P.S. Hallman, T.A. Stephenson and G. Wilkinson, Inorg. Synth. 12 (1970) 237.

    Google Scholar 

  21. L. Vaska, J. Amer. Chem. Soc. 86 (1964) 1943.

    Google Scholar 

  22. S.S. Berman and R. Ironside, Can. J. Chem. 36 (1958) 1151.

    Google Scholar 

  23. V.I. Shlenskaya, V.P. Khostova and V.M. Peshkova, Zh. Anal. Khim. 17 (1962) 598.

    Google Scholar 

  24. G.H. Ayres and A.S. Mayer, Anal. Chem. 23 (1951) 299.

    Google Scholar 

  25. J.L. Woodhead and J.M. Fletcher, J. Chem. Soc. (1961) 5039.

  26. G.H. Ayres and W.N. Wells, Anal. Chem. 22 (1950) 317.

    Google Scholar 

  27. A. Jegorov, B. Kratochvíl, V. Langer and J. Podlahová, Inorg. Chem. 23 (1984) 4288.

    Google Scholar 

  28. A. Jegorov, J. Podlaha, J. Podlahová and F. Tureček, J. Chem. Soc., Dalton Trans. (1990) 3259.

  29. M.M.T. Khan and Md.K. Nazeeruddin, Inorg. Chim. Acta 147 (1988) 33.

    Google Scholar 

  30. J. Růžičková and J. Podlahová, Coll. Czech. Chem. Commun. 43 (1978) 2853.

    Google Scholar 

  31. J. Pangrác and J. Podlahová, Coll. Czech. Chem. Commun. 46 (1981) 1222.

    Google Scholar 

  32. J.P. Chandlin and A.R. Oldham, Discuss. Faraday Soc. 46 (1968) 60.

    Google Scholar 

  33. M. Polievka, L. Uhlár and V. Macho, Petrochemia 18 (1978) 9.

    Google Scholar 

  34. J. Farrar, D. Holland and D.J. Milner, J. Chem. Soc., Dalton Trans. (1975) 815.

  35. S.N. Backburn, R.N. Haszeldine r.N, R.V. Parish and J.H. Setchfield, J. Organometal. Chem. 192 (1980) 329.

    Google Scholar 

  36. K. Kaneda, T. Uchiyama, Y. Fujiwara, T. Imanaka and S. Teranishi, J. Org. Chem. 44 (1979) 55.

    Google Scholar 

  37. D. Bingham, B. Hudson, D.E. Webster and P.B. Wells, J. Chem. Soc., Dalton Trans. (1974) 1521.

  38. J.W. Fitch, W.G. Payne and D. Westmoreland, J. Org. Chem. 48 (1983) 751.

    Google Scholar 

  39. A. Millan, E. Towns and P.M. Maitlis, J. Chem. Soc., Chem. Commun. (1981) 673.

  40. H. Matsumoto, T. Nakano, T. Takatsu and Y. Nagai, J. Org. Chem. 43 (1978) 1734.

    Google Scholar 

  41. R.A. Sánches-Delago, A. Andriollo and N. Valencia, Chem. Commun. (1983) 444.

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Authors and Affiliations

  1. South Bohemian Biological Centre, Czechoslovak Academy of Sciences, Branišovská 31, 370 05, České, Budějovice

    Alexandr Jegorov & Jaroslav Podlaha

  2. Department of Inorganic Chemistry, Charles University, 128 40 Prague 2, Czechoslovakia

    Alexandr Jegorov & Jaroslav Podlaha

Authors
  1. Alexandr Jegorov
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  2. Jaroslav Podlaha
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Jegorov, A., Podlaha, J. Regeneration of platinum-metal-based catalysts with carboxyphosphines as extractants. Catal Lett 9, 9–14 (1991). https://doi.org/10.1007/BF00769075

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