Catalysis Letters

, Volume 19, Issue 4, pp 361–367 | Cite as

Carbonaceous fragments of osmium ligand deficient clusters that take part in alkane C-H and C-C bonds cleavage in the presence of molecular hydrogen

  • I. S. Akhrem
  • N. M. Chistovalova
  • M. F. Polubentseva
  • I. E. Pikersky
  • Yu. G. Dubinskyt
  • M. E. Vol'pin
Article
  • 26 Downloads

Abstract

The direct participation of carbonaceous ligands of osmium ligand deficient clusters (LDC) in alkane and cycloalkane reactions in the presence of H2 is proved by14C-labeling. In contrast to the other metallic catalysts, wherein carbonaceous ligands block active centres, the C-containing ligands of the Os-LDC are active and exhibit at least two functions in alkane and cycloalkane reactions: stabilization of clusters against agglomeration and preservation of active centres.

Keywords

14C/12C exchange alkane C-H and C-C bond activation carbonaceous ligands osmium ligand deficient clusters 

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Copyright information

© J.C. Baltzer AG, Science Publishers 1993

Authors and Affiliations

  • I. S. Akhrem
    • 1
  • N. M. Chistovalova
    • 1
  • M. F. Polubentseva
    • 1
  • I. E. Pikersky
    • 1
  • Yu. G. Dubinskyt
    • 1
  • M. E. Vol'pin
    • 1
  1. 1.A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of SciencesMoscowRussia

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