Abstract
Ionic alkali clusters such as Na 3+4 produced as (dark purple) zeolites under mild conditions efficiently activate carbon monoxide even at −130 ° C. The well-resolved ESR spectra showing both23Na and13C hyperfine splittings provide structural insight into the initial CO interaction.
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Yoon, K.B., Kochi, J.K. Facile reduction of carbon monoxide in zeolites by ionic sodium clusters. Catal Lett 1, 183–189 (1988). https://doi.org/10.1007/BF00766172
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DOI: https://doi.org/10.1007/BF00766172