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Single crystal modelling of the SMSI phenomenon: Structure, composition, electronic effects and CO chemisorption at the Ru(0001)/TiOx interface

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Abstract

LEED, CO chemisorption, Auger and XP spectroscopy have been used to investigate the growth morphology, structure, kinetic behaviour and chemical properties of TiO x films on Ru(0001) as a function of oxide loading and temperature. The system exhibits a number of interesting properties which are of direct relevance to the SMSI phenomenon; these properties are critically dependent on the method of preparation.

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Author notes

  1. Andrew J. Gellman

    Present address: School of Chemical Sciences, University of Illinois at Urbana-Champaign, 505 S, Mathews Avenue, 61801, Urbana, Ill., USA

Authors and Affiliations

  1. Department of Physical Chemistry, University of Cambridge, CB2 1EP, Cambridge, England

    Jas Pal S. Badyal, Andrew J. Gellman, Robert W. Judd & Richard M. Lambert

Authors
  1. Jas Pal S. Badyal
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  2. Andrew J. Gellman
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  3. Robert W. Judd
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  4. Richard M. Lambert
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Badyal, J.P.S., Gellman, A.J., Judd, R.W. et al. Single crystal modelling of the SMSI phenomenon: Structure, composition, electronic effects and CO chemisorption at the Ru(0001)/TiOx interface. Catal Lett 1, 41–50 (1988). https://doi.org/10.1007/BF00765352

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  • DOI: https://doi.org/10.1007/BF00765352

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