Abstract
This study is concerned with the effect of various amounts of Sn species in modifying the surface acidic and basic properties of alumina, important in catalytic activity. The decomposition of isopropanol and conversion of cumene were chosen as a measure of the changes to the acidic/basic catalytic sites, and the adsorption of pyridine (measured by IR spectroscopy) to separate out the Brønsted and Lewis acid activity.
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F.H. van Cauwelaert and W.K. Hall, Trans. Faraday Soc. 66 (1970) 457.
J.W. Hightower and W.K. Hall, Trans. Faraday Soc. 60 (1970) 477.
D.S. Maciver, W.H. Wilmot and J.M. Bridges, J. Catal. 3 (1964) 502.
P.M. Boorman, K. Chong, R.A. Kydd and J.M. Levis, J. Catal. 128 (1991) 537.
H. Knözinger, Adv. Catal. 25 (1976) 184.
J.M. Dumas, C. Geron, A. Kribii and J. Barbier, Appl. Catal. 47 (1989) L9.
P. Berteau, S. Ceckiewicz and B. Delmon, Appl. Catal. 31 (1987) 361.
P. Berteau, M.A. Kellens and B. Delmon, J. Chem. Soc. Faraday Trans. 7 (1991) 1425.
Y.X. Li and K.J. Klabunde, J. Catal. 126 (1990) 173.
Y.X. Li, K.J. Klabunde and B.H. Davis, J. Catal. 128 (1991) 1.
J. Margitfalvi, M. Hegedus, S. Gobolos, E. Kern-Talas, P. Szedlacsek, S. Szabo and F. Nagy, in:Proc. 8th Int. Congr. on Catalysis, Vol. 4, Berlin 1984 (Verlag Chemie, Weinheim, 1984) p. 903.
E. Kern-Talas, M. Hegedus, S. Gobolos, P. Szedlacsek and J. Margitfalvi, in:Preparation of Catalysts IV, eds. B. Delmon, P. Grange, P.A. Jacobs and G. Poncelet (Elsevier, Amsterdam, 1987) p. 689.
Cs. Vertes, E. Talas, I. Czako-Nagy, J. Ryczkowski, S. Gobolos, A. Vertes and J. Margitfalvi, Appl. Catal. 68 (1991) 149.
G. Meitzner, G.H. Via, F.W. Lytle, S.C. Fung and J.H. Sinfelt, J. Phys. Chem. 92 (1988) 2925.
O. Beeck, Discussions Faraday Soc. 8 (1950) 118.
P. Kirszensztejn, Mat. Chem. Phys. 27 (1991) 117.
P. Kirszensztejn, Mat. Chem. Phys. 27 (1991) 129.
T.H. Ballinger and J.T. Yates Jr., J. Phys. Chem. 96 (1992) 1417.
I. Mochida, A. Uchino, H. Fujitsu and K. Takeshita, J. Catal. 51 (1978) 72.
P. Kirszenstejn and S. Zielinski, Polish Patent WP-216-275654 (1988).
P. Kirszenstejn, L. Wachowski and S. Zielinski, Polish Patent WP-217-275653 (1988).
T.P. Beebe Jr., J.E. Crowell and J.T. Yates Jr., J. Phys. Chem. 92 (1988) 1296.
P.O. Scocart, F.D. Declerck, R.E. Sempels and P.G. Rouxhet, J. Chem. Soc. Faraday Trans. I 73 (1977) 359.
H. Knözinger and P. Ratnasamy, Catal. Rev.-Sci. Eng. 17 (1978) 31.
J.A.R. van Veen, G. Jonkers and W.H. Hesseling, J. Chem. Soc. Faraday Trans. I 85 (1989) 389.
E.P. Parry, J. Catal. 2 (1963) 371.
K. Nakamoto, in:Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th Ed. (Wiley-Interscience, New York, 1986).
M.C. Kung and H.H. Kung, Catal. Rev.-Sci. Eng. 27 (1985) 425.
A. Corma, V. Fornes and E. Ortega, J. Catal. 92 (1985) 284.
M.B. Fleisher, L.O. Golender and M.V. Shimanskaya, J. Chem. Soc. Faraday Trans. 87 (1991) 745.
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Kirszensztejn, P., Przystajko, W. & Bell, T.N. Al2O3-SnO2 systems as a support for metallic catalysts. III. Acid-base properties of modified aluminas. Catal Lett 18, 391–399 (1993). https://doi.org/10.1007/BF00765285
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DOI: https://doi.org/10.1007/BF00765285