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Influence of solvents on hydration of 1,2-epoxyhexane overH-ZSM-5-C18 catalyst

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Abstract

The influence of solvents such as benzene, toluene,m-xylene, and neighbours on the hydration of 1,2-epoxyhexane caused by the pore ofH-ZSM-5-C18 catalyst was studied by measurement of the reaction rate. The largest retardation of the hydration was observed usingm-xylene as solvent. Any other solvents did not show so large a retardation as that ofm-xylene. By taking advantage of the retardation withm-xylene the effect of the pores of various types of zeolites on the rate could be dynamically demonstrated.

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Authors and Affiliations

  1. Department of Chemistry, Tokyo Gakugei University, Koganei, 184, Tokyo, Japan

    Haruo Ogawa & Kohshi Sawamura

  2. The Institute of Physical and Chemical Research (RIKEN), Wako, 351-01, Saitama, Japan

    Teiji Chihara

Authors
  1. Haruo Ogawa
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  2. Kohshi Sawamura
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  3. Teiji Chihara
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Ogawa, H., Sawamura, K. & Chihara, T. Influence of solvents on hydration of 1,2-epoxyhexane overH-ZSM-5-C18 catalyst. Catal Lett 18, 367–371 (1993). https://doi.org/10.1007/BF00765283

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  • DOI: https://doi.org/10.1007/BF00765283

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