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Stability of the tetrahedral aluminium sites in zeolite beta

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Abstract

Calcination of as-synthesized or ammonium-exchanged forms of zeolite BETA induces an extensive loss of framework aluminium evidenced by27Al MAS NMR, XRD and FTIR spectroscopies. Treatment of the calcined solids in ammonium nitrate restores the tetrahedral Al sites. Material balances show that the latter process is quantitative.

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Authors and Affiliations

  1. Laboratoire de Chimie Organique Physique et Cinétique Chimique Appliquées, URA 418 du CNRS, ENSCM, 8, rue de l'Ecole Normale, 34053, Montpellier Cedex 1, France

    Elodie Bourgeat-Lami, Pascale Massiani, Francesco Di Renzo & François Fajula

  2. Centre de Recherches ELF France, BP 20, 69360, St. Symphorien D'Ozon, France

    Thierry Des Courieres

Authors
  1. Elodie Bourgeat-Lami
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  2. Pascale Massiani
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  3. Francesco Di Renzo
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  4. François Fajula
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  5. Thierry Des Courieres
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Bourgeat-Lami, E., Massiani, P., Di Renzo, F. et al. Stability of the tetrahedral aluminium sites in zeolite beta. Catal Lett 5, 265–271 (1990). https://doi.org/10.1007/BF00764671

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  • DOI: https://doi.org/10.1007/BF00764671

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