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Octadecyl immobilized H-ZSM-5-catalyzed ring-openings of epoxides with water in liquid phase accompanying shape-selective property

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Abstract

The octadecyltrichlorosilane-treated ZSM-5 catalyst H-ZSM-5-C18 exhibited high activity in the ring-opening reaction of epoxides in a toluene-water solvent. The shape-selective property of H-ZSM-5-C18 in the liquid phase has also been observed by comparing the reaction rates with those over octadecyltrichlorosilane treated SiO2-Al2O3.

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References

  1. G.H. Posner, Angew. Chem. Int. Ed. 17 (1978) 487;

    Google Scholar 

  2. A. McKillop and D.W. Young, Synthesis (1979) 401, 481;

  3. A. Cornelis and P. Laszlo, Synthesis (1985) 909;

  4. M. Hojo, Yuki Gosei Kagaku Kyokai Shi 42 (1984) 635;

    Google Scholar 

  5. H. Ogawa, Hyomen Kagaku 11 (1990) 124.

    Google Scholar 

  6. V. Ramamurthy, D.R. Corbin and D.F. Eaton, J. Chem. Soc. Chem. Commun. (1989) 1213;

  7. D.R. Corbin, D.F. Eaton, and V. Ramamurthy, J. Org. Chem. 53 (1988) 5384.

    Google Scholar 

  8. N.J. Turro, C.-C. Cheng, L. Abrams and D.R. Corbin, J. Am. Chem. Soc. 109 (1987) 2449;

    Google Scholar 

  9. N.J. Turro and P. Wan, J. Am. Chem. Soc. 107 (1985) 678;

    Google Scholar 

  10. N.J. Turro, C.-C. Cheng, and X.-G. Lei, J. Am. Chem. Soc. 107 (1985) 3739.

    Google Scholar 

  11. M. Onaka, K. Sugita, H. Takeuchi and Y. Izumi, J. Chem. Soc. Chem. Commun. (1988) 1173.

  12. D. Fraenkel and Moshe Levy, J. Catal. 118 (1989) 10.

    Google Scholar 

  13. R. Kumar and P. Ratnasamy, J. Catal. 118 (1989) 68.

    Google Scholar 

  14. H. Ogawa, K. Tensai, K. Taya and T. Chihara, J. Chem. Soc. Chem. Commun. (1990) 1246.

  15. W.R. Suprine, R.S. Henly and R.F. Kruppa, J. Am. Oil Chemists' Soc. 43 (1966) 202A;

    Google Scholar 

  16. J.F. Fritz and J.N. King, Anal. Chem. 48 (1976) 570.

    Google Scholar 

  17. S. Namba, N. Hosonuma and T. Yashima, J. Catal. 72 (1981) 16.

    Google Scholar 

  18. P. de Mayo, Pure Appl. Chem. 54 (1982) 1623.

    Google Scholar 

  19. N.J. Turro, Tetrahedron 43 (1987) 1589.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Tokyo Gakugei University, Koganei, 184, Tokyo, Japan

    Haruo Ogawa & Kohshi Sawamura

  2. The Institute of Physical and Chemical Research (R1KEN), Wako, 351-01, Saitama, Japan

    Teiji Chihara

Authors
  1. Haruo Ogawa
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  2. Kohshi Sawamura
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  3. Teiji Chihara
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Ogawa, H., Sawamura, K. & Chihara, T. Octadecyl immobilized H-ZSM-5-catalyzed ring-openings of epoxides with water in liquid phase accompanying shape-selective property. Catal Lett 16, 39–42 (1992). https://doi.org/10.1007/BF00764352

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  • DOI: https://doi.org/10.1007/BF00764352

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