Skip to main content
SpringerLink
Log in

Immobilization of HRh(CO)(P(m-C6H4SO3Na)3)3 on an anion exchange resin for the hydroformylation of higher olefins

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

The anion exchange resin Amberlyst, A-26, forms an efficient matrix for the immobilization of the water soluble complex, HRh(CO)(m-C6H4SO3Na)3)3. Catalysis proceeds in anhydrous alcohol solvents which allows the conversion of water insoluble olefins to aldehydes. Activities and selectivities are similar to both supported aqueous phase catalysts and to the neutral complex, HRh(CO)(PPh3)3 in non-aqueous solvents. The catalyst preparation minimizes the quantity of water in the supported catalyst; the lack of water is thought to be responsible for an increase in catalyst stability toward oxidation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. Masters,Homogeneous Catalysis, A Gentle Art, 1980.

  2. M. Matsumoto and M. Tamura, J. Mol. Catal. 19 (1983) 365.

    Google Scholar 

  3. E. Kuntz, U.S. Patent 4, 246, 802;

  4. E. Kuntz, German Patent 2,627,354;

  5. E. Kuntz, French Patent 2,314,910;

  6. E. Kuntz, Netherlands Patent, 7,606,634;

  7. E. Kuntz, Chemtech 17 (1987) 570.

    Google Scholar 

  8. A.F. Borowski, D.J. Cole-Hamilton and G. Wilkinson, J. Nouv. Chim. 2 (1978) 137.

    Google Scholar 

  9. J.P. Arhancet, M.E. Davis, J.S. Merola and B.E. Hanson; Nature (London) 339 (1989) 454;

    Google Scholar 

  10. J.P. Arhancet, M.E. Davis, J.S. Merola and B.E. Hanson; J. Catal. 121 (1990) 327;

    Google Scholar 

  11. J.P. Arhancet, M.E. Davis and B.E. Hanson, U.S. Patent 4,347,003.

  12. J.P. Arhancet, M.E. Davis and B.E. Hanson; J. Catal., accepted.

  13. I.T. Horvath, Catal. Lett. 6 (1990) 43.

    Google Scholar 

  14. C. Larpent, R. Dabard and H. Patin, Inorg. Chem. 26 (1987) 2922.

    Google Scholar 

  15. R.T. Smith, R.K. Ungar and M.C. Baird, Transition Metal Chem. 7 (1982) 288.

    Google Scholar 

  16. S.C. Tang, T.E. Paxson and L. Kim, J. Mol. Catal. 9 (1980) 313;

    Google Scholar 

  17. L. Kim, T.E. Paxson and S.C. Tang, U.S. Patents 4,179,402; 4,179,403; 4,317,936.

  18. F. Joo and M.T. Beck, J. Mol. Catal. 24 (1984) 135.

    Google Scholar 

  19. I. Toth, B.E. Hanson and M.E. Davis, J. Organomet. Chem. (1987) 109.

Download references

Author information

Authors and Affiliations

  1. the Departments of Chemistry and Chemical Engineering, Virginia Polytechnic Institute and State University, 24061, Blacksburg, Virginia, USA

    Imre Toth, Brian E. Hanson, Ipin Guo & Mark E. Davis

Authors
  1. Imre Toth
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Brian E. Hanson
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ipin Guo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Mark E. Davis
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Toth, I., Hanson, B.E., Guo, I. et al. Immobilization of HRh(CO)(P(m-C6H4SO3Na)3)3 on an anion exchange resin for the hydroformylation of higher olefins. Catal Lett 8, 209–214 (1991). https://doi.org/10.1007/BF00764118

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00764118

Keywords

Search

Navigation