Skip to main content
Log in

Enhancement of the n-butane aromatization activity of ZSM-5 zeolite by incorporation of alpha-quartz

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

It is shown that pure alpha-quartz used as co-catalyst can enhance the aromatization activity of ZSM-5 zeolite.

Higher conversion of n-butane and higher production of aromatics and molecular hydrogen are obtained when higher amounts of quartz are embedded within the hybrid catalyst and when the particle size of quartz is smaller.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Chemistry in Britain 20 (1984) 684.

  2. P.C. Doolan and P.R. Pujado, Hydroc. Process. (September 1989) 72.

  3. D.C. Martindale, P.J. Kuchar and R.K. Olson, AICHE, Summer Nat. Meeting, Denver (U.S.A.), Aug. 21–24 (1988).

  4. A.W. Chester, U.S. Pat 4 350 835 (Sep. 21, 1982).

  5. H. Kitagawa, Y. Sedola and Y. Ono, J. Catal. 101 (1986) 12.

    Google Scholar 

  6. N.S. Gnep, J.Y. Doyemet, A.M. Seco, F.R. Ribeiro and M. Guisnet, Appl. Catal. 43 (1988) 155.

    Google Scholar 

  7. M.S. Scurell, Appl. Catal. 41 (1988) 89.

    Google Scholar 

  8. K. Fujimoto, I. Nakamura and K. Yokota, in:Proc. Sec. Int. Conf. on Spillover, ed. K.H. Steinberg (Leipzig, GDR), (June 12–16, 1989) 176.

  9. Y. Ono, H. Nakatani and E. Suzuki, in:Successful Design of Catalysts, ed. T. Inui (Elsevier Sc. Publ., 1988) 279.

  10. R. Le Van Mao and L. Dufresne, Third Chemical Congress of North America, Toronto (Canada), June 5–10 (1988);

  11. R. Le Van Mao and L. Dufresne, Appl. Catal. 52 (1989) 1;

    Google Scholar 

  12. R. Le Van Mao and L. Dufresne, U.S. Pat. 4 975 402 (Dec. 4, 1990).

  13. J. Yao, R. Le Van Mao and L. Dufresne, Appl. Catal. 65 (1990) 175.

    Google Scholar 

  14. R. Le Van Mao, L. Dufresne and J. Yao, AICHE Spring Nat. Meeting, Houston (U.S.A.), April 2–6 (1989);

  15. R. Le Van Mao, L. Dufresne and J. Yao, Appl. Catal. 65 (1990) 143.

    Google Scholar 

  16. R. Le Van Mao and J. Yao, Catal. Lett. 6 (1990) 23.

    Google Scholar 

  17. R. Le Van Mao and J. Yao, Appl. Catal., in press.

  18. G.L. Price and V. Kanazirev, J. Catal. 126 (1990) 267.

    Google Scholar 

  19. P. Meriaudeau and C. Naccache, Appl. Catal. 73 (1991) L13.

    Google Scholar 

  20. V. Kanazirev, V. Mavrodinova, I. Kosova and G.L. Price, Catal. Lett. 9 (1991) 35.

    Google Scholar 

  21. K. Seshan, Appl. Catal. 55 (1989) N4.

    Google Scholar 

  22. R.L. Argauer and G.R. Landolt, U.S. Pat. 3 702 886 (1972).

  23. G.C. Bond, in:Spillover of Adsorbed Species, eds. G.M. Pajonk, S.J. Teichner and J.E. Germain (Elsevier Sc. Publ., Amsterdam, The Netherlands, 1983) 1.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yao, J., Le Van Mao, R. Enhancement of the n-butane aromatization activity of ZSM-5 zeolite by incorporation of alpha-quartz. Catal Lett 11, 191–197 (1991). https://doi.org/10.1007/BF00764085

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00764085

Keywords

Navigation