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Role of defect structure of active oxides in oxidative coupling of methane

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Abstract

A new approach to the choice of catalysts for oxidative coupling of methane based on the determination of the defect degree is suggested. For the most active catalysts (oxides of rare earth elements (REE), alkaline earth metals (AEM), manganese, lead), it is shown that oxygen defectness is of great importance in this process.

Based on the structural approach Bi2O3-containing catalytic systems have been suggested. They have C2-hydrocarbon formation activity and selectivity to be comparable with those ones for most active catalysts as REE oxides.

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References

  1. C.H. Lin, K.D. Campbell, J.-X. Wang and G.H. Lunsford, J. Catal. 90 (1986) 534.

    Google Scholar 

  2. K. Otsuka and K. Jinno, Inorg. Chem. Acta 121 (1986) 237.

    Google Scholar 

  3. D.J. Driscoll, W. Martin, J.-X. Wang and J.H. Lunsford, J. Amer. Chem. Soc. 107 (1985) 58.

    Google Scholar 

  4. V.D. Sokolovskii, S.M. Aliev, O.V. Buevskaya and A.A. Davydov, Catal. Today 4 (1989) 293.

    Google Scholar 

  5. A.G. Anshits, N.P. Kirik, V.G. Roguleva, A.N. Shigapov and G.E. Selyutin, Catal. Today 4 (1989) 399.

    Google Scholar 

  6. K. Otsuka, K. Jinno and A. Morikawa, J. Catal. 100 (1986) 353.

    Google Scholar 

  7. K.D. Campbell, H. Zhang and J.H. Lunsford, J. Phys. Chem. 92 (1988) 750.

    Google Scholar 

  8. S.J. Korf, J.M. Roos, J.M. Diphoorn, R.H.J. Veenof, J.G. van Ommen and J.R.H. Ross, Catal. Today 4 (1989) 279.

    Google Scholar 

  9. V.P. Zhereb, Dissertation, Institute of General and Nonorganic Chemistry, Moskow, 1980 (in Russ.).

    Google Scholar 

  10. A.F. Wells,Structural Inorganic Chemistry (Oxford University Press, Oxford, 1984).

    Google Scholar 

  11. A.M. Gaffney, C.A. Jones, J.J. Leonard and J.A. Sofranko, J. Catal. 114 (1988) 422.

    Google Scholar 

  12. Yu.D. Tret'yakov,Chemistry of Nonstoichiometries Oxides (Moscow University, Moscow, 1974) (in Russ.).

    Google Scholar 

  13. P. Kofstad,Nonstoichiometry, Diffusion and Electrical Conductivity in Binary Metal Oxides (Wiley-Interscience, New York, 1972).

    Google Scholar 

  14. S.G. Yusupova, V.B. Glushkova, P.A. Tikhonov, A.N. Mosevich and M.V. Kalinina, J. Phys. Chem. Acad. Sci. USSR 62 (1988) 2534 (in Russ.).

    Google Scholar 

  15. A.Yu. Loginov, S.E. Spiridonov, Kh.K. Chokaev and I.N. Filimonov, J. Phys. Chem. Acad. Sci. USSR 62 (1988) 3235 (in Russ.).

    Google Scholar 

  16. E.K. Chang, and R.N. Blumental, J. Solid State Chemistry 72 (1988) 330.

    Google Scholar 

  17. V. Tohg, M.P. Rosynek and J.H. Lunsford, J. Phys. Chem. 93 (1989) 2896.

    Google Scholar 

  18. K. Hauffe,Reaktionen in und an Festen Stoffen (Springer-Verlag, Berlin-Göttingen-Heidelberg, 1955).

    Google Scholar 

  19. A.Yu. Loginov, S.V. Kostikov, N. Krush and K.V. Topchieva, Vestnik Moskovskogo Universiteta 20 (1979) 216 (in Russ.).

    Google Scholar 

  20. A.G. Anshits, V.G. Roguleva, E.N. Voskresenskaya, G.E. Selutin and V.V. Rivanenkov, 1-st Tokyo Conf. on Advanced Catalytic Science and Technology. July 1–5, 1990 (in press).

  21. P. Martens, H. Gentsch and F. Freund, J. Catal. 44 (1976) 366.

    Google Scholar 

  22. A.G. Anshits, E.N. Voskresenskaya and A.N. Shigapov, Preprints 3-d Symp. on Methane Activation, Conversion and Utilization. 1989. Honolulu, Hawaii.

  23. W. Ueda and J.M. Thomas,Proc. 9th Int. Congr. Catal., Calgary, Canada, Vol. 2 (1988) 960.

    Google Scholar 

  24. C.-H. Lin, T. Ito, J.-X. Wang and J.H. Lunsford, J. Amer. Chem. Soc. 109 (1987) 4808.

    Google Scholar 

  25. E. Iwamatsu, T. Moriyama, N. Takasaki and K. Aika, J. Catal. 113 (1989) 25.

    Google Scholar 

  26. A.G. Anshits, N.P. Kirik, V.G. Roguleva, G.E. Selyutin and E.A. Proshina,Proc. 3-d Indo-Soviet Seminar on Catalysis, Novosibirsk, Vol. 1 (1988) 39.

    Google Scholar 

  27. M.J. Verkerk, K. Keizer and A.J. Burggraaf, J. Appl. Electrochem. 10 (1980) 80.

    Google Scholar 

  28. T.H. Etsell and S.N. Flengas, Chem. Rev. 70 (1970) 339.

    Google Scholar 

  29. K. Machida and M. Enyo, J. Chem. Soc., Chem. Commun. 21 (1987) 1639.

    Google Scholar 

  30. B. Aurivillius and L.G. Sillen, Nature 155 (1945) 305.

    Google Scholar 

  31. J.M. Deboy and R.F. Hicks, J. Catal. 113 (1988) 517.

    Google Scholar 

  32. N.Yu. Sinev, V.N. Korchak and O.V. Krylov,Proc. 9th Int. Congr. Catal, Calgary, Canada, Vol. 2 (1988) 968.

    Google Scholar 

  33. K. Otsuka and T. Komatsu, Chem. Lett. (1987) 483.

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Authors and Affiliations

  1. Institute of Chemistry & Chemical Technology, K. Marx street 42, 660049, Krasnoyarsk, USSR

    A. G. Anshits, E. N. Voskresenskaya & L. I. Kurteeva

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  1. A. G. Anshits
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  2. E. N. Voskresenskaya
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  3. L. I. Kurteeva
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Anshits, A.G., Voskresenskaya, E.N. & Kurteeva, L.I. Role of defect structure of active oxides in oxidative coupling of methane. Catal Lett 6, 67–75 (1990). https://doi.org/10.1007/BF00764054

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