Journal of Structural Chemistry

, Volume 30, Issue 5, pp 748–755 | Cite as

Electron diffraction, x-ray diffraction, and CNDO/2 analysis of the conformations, molecular geometry, and internal rotation potentials of aryldichloro- and aryldibromoarsines

  • N. M. Zaripov
  • R. G. Khusnutdinov
  • I. A. Litvinov
  • L. V. Ermolaeva
  • V. A. Naumov
Article

Abstract

A structural study was carried out on o-ClC6H4AsCl2 (I), o-BrC6H4AsBr2 (II), C6H5AsBr2 (III), and p-BrC6H4AsBr2 (IV). The normal mode frequencies and shapes were calculated and gas-phase electron diffraction was used to establish the geometric parameters of III and IV. The structure of IV was determined by x-ray diffraction structural analysis. The experimental results for I–IV (I and II were studied in previous work) were interpreted on the basis of CNDO/2 calculations for I–III.

Keywords

Physical Chemistry Inorganic Chemistry Structural Analysis Geometric Parameter Mode Frequency 

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • N. M. Zaripov
  • R. G. Khusnutdinov
  • I. A. Litvinov
  • L. V. Ermolaeva
  • V. A. Naumov

There are no affiliations available

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