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Journal of Structural Chemistry

, Volume 34, Issue 2, pp 306–322 | Cite as

Specific nonbonded interactions in the structures of M3X74+ and M3X44+ (M=Mo, W; X=O, S, Se) clusters

  • A. V. Virovets
  • N. V. Podberezskaya
Review

Abstract

Specific nonbonded interactions (SNI) involving the chalcogens in the structures of (μ3−X)(μ2−X2)3M34+ and (μ3−X)(μ2−X)3M34+ (M = Mo, W; X = 0, S, Se) clusters are examined. Interionic contacts significantly shorter than the sum of the van der Waals or ionic radii are fomd between the X atom of the X2 ligands that occupy the axial position relative to the M3 plane and the N, chalcogen, or halide of the counterion or identical ion. Centrosymmetric dimers involving the (μ2-X2) ligands are observed in the stmctures of several M3X44+ derivatives. The X...X distance in these is also much less than the sum of the van der Waals radii. These SNI open occur in spite of the Coulombic repulsion of similarly charged species. The SNZ are classified using existing data. They play a definite role in forming of the crystal structure.

Keywords

Physical Chemistry Crystal Structure Inorganic Chemistry Ionic Radius Halide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • A. V. Virovets
  • N. V. Podberezskaya

There are no affiliations available

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