Conclusions
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1.
The polarographic behavior of anhydrovitamin A has been studied. In agreement with the result of a calculation of charge distribution by the LCAOMO method in Huckel's approximation it has been found that the kinetic basicity of the anion radical of anhydrovitamin A is lower than that of shorter conjugated sysems.
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2.
A procedure for determining anhydrovitamin A in the presence of vitamin A acetate using derivative oscillographic voltammetry has been proposed, and the possibility of using this method for the direct analysis of a mixture of esters of vitamin A with anhydrovitamin A and esters of retrovitamin A has been shown.
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Translated from Khimiko-Farmatsevticheskii Zhurnal, No. 11, pp. 51–54, November, 1968.
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Valashek, I.E., Mairanovskii, V.G., Shakhova, M.K. et al. Polarographic determination of vitamin A acetate in the presence of anhydrovitamin A. Pharm Chem J 2, 639–642 (1968). https://doi.org/10.1007/BF00760290
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DOI: https://doi.org/10.1007/BF00760290