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Reactions of aldehydes of the furan series. 3. Oxidative-reductive conversions on the surface of alkali granules

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Furan aldehydes undergo an oxidative-reductive disproportionation over solid alkali in a solvent inert to alkali. Molecular oxygen increases the yield of the furan carboxylic acid. A reaction scheme is proposed that takes into account the important role of alcoholates of gem-polyols.

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Authors and Affiliations

  1. Krasnodar Polytechnic Institute, 350670, Krasnodar

    Yu. M. Shapiro, V. P. Smolyakov & V. G. Kul'nevich

Authors
  1. Yu. M. Shapiro
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  2. V. P. Smolyakov
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  3. V. G. Kul'nevich
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Additional information

For Communication 2, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 741–744, June, 1990.

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Shapiro, Y.M., Smolyakov, V.P. & Kul'nevich, V.G. Reactions of aldehydes of the furan series. 3. Oxidative-reductive conversions on the surface of alkali granules. Chem Heterocycl Compd 26, 617–620 (1990). https://doi.org/10.1007/BF00756409

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  • DOI: https://doi.org/10.1007/BF00756409

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