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Cleavage of the aziridine ring

II. Reaction of N-phenylethyleneimine with isothiocyanates

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

On reaction with N-phenylethyleneimine in the presence of tetraethylammonium bromide, methyl and phenyl isothiocyanates form 2-methyl- and 2-phenyl-imino-3-phenylthiazolidines. In this reaction, methyl isothiocyanate partially trimerizes. Under the action of N-phenylethyleneimine phenylisocyanate trimerizes in high yield.

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For part I, see [9].

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Sineokov, A.P., Gladysheva, V.N. & Etlis, V.S. Cleavage of the aziridine ring. Chem Heterocycl Compd 4, 418–420 (1968). https://doi.org/10.1007/BF00755307

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  • DOI: https://doi.org/10.1007/BF00755307

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