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Chemistry of Heterocyclic Compounds

, Volume 4, Issue 3, pp 415–416 | Cite as

Nitrogen-containing organosilicon compounds

XI. Dipole moments and structure of some azasilacyclanes
  • I. B. Mazheika
  • L. I. Libert
  • E. Lukevits
  • M. G. Voronkov
Brief Communications

Abstract

The dipole moments of 1-ethoxy-2-carbasilatrane (1-ethoxy-2,8-dioxa-5-aza-1-silabicyclo [3,3,3]undecane (II)), and of 1,1-dimethyl-2,8-dioxa-5-aza-1-silacyclooctane (III) have been investigated. The presence of a transannular Si ← N coordination bond (weaker than in the 1-ethoxysilatrane 1) in II and its absence from III has been established.

Keywords

Organic Chemistry Dipole Moment Coordination Bond Undecane Organosilicon Compound 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© The Faraday Press, Inc. 1970

Authors and Affiliations

  • I. B. Mazheika
    • 1
  • L. I. Libert
    • 1
  • E. Lukevits
    • 1
  • M. G. Voronkov
    • 1
  1. 1.Institute of Organic Synthesis AS Latvian SSRRiga

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