Chemistry of Heterocyclic Compounds

, Volume 4, Issue 3, pp 415–416 | Cite as

Nitrogen-containing organosilicon compounds

XI. Dipole moments and structure of some azasilacyclanes
  • I. B. Mazheika
  • L. I. Libert
  • E. Lukevits
  • M. G. Voronkov
Brief Communications


The dipole moments of 1-ethoxy-2-carbasilatrane (1-ethoxy-2,8-dioxa-5-aza-1-silabicyclo [3,3,3]undecane (II)), and of 1,1-dimethyl-2,8-dioxa-5-aza-1-silacyclooctane (III) have been investigated. The presence of a transannular Si ← N coordination bond (weaker than in the 1-ethoxysilatrane 1) in II and its absence from III has been established.


Organic Chemistry Dipole Moment Coordination Bond Undecane Organosilicon Compound 
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Copyright information

© The Faraday Press, Inc. 1970

Authors and Affiliations

  • I. B. Mazheika
    • 1
  • L. I. Libert
    • 1
  • E. Lukevits
    • 1
  • M. G. Voronkov
    • 1
  1. 1.Institute of Organic Synthesis AS Latvian SSRRiga

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