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Synthesis of organocyclosiloxanes containing cyanoalkyl groups on the silicon atom

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The cohydrolysis ofΒ-cyanoethyl- andγ-cyanopropylmethyldichlorosilanes with dimethyldichlorosilane has been studied and the optimum conditions ensuring the maximum yield of rings containing cyanoalhyl groups have been determined.

B is(Β-cyanoethyl)hexamethylcyclotetrasiloxane,γ-cyanopropylpentamethylcyclotetrasiloxane, and bis(γ-cyanopropyl)hexamethylcyclotetrasiloxane have been obtained for the first time and characterized.

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Ponomarev, A.I., Klebanskii, A.L., Larionova, Y.A. et al. Synthesis of organocyclosiloxanes containing cyanoalkyl groups on the silicon atom. Chem Heterocycl Compd 4, 318–320 (1968). https://doi.org/10.1007/BF00755267

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  • DOI: https://doi.org/10.1007/BF00755267

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